MoTe2 is a Weyl semimetal, which exhibits unique non-saturating magnetoresistance and strongly reinforced superconductivity under pressure. Here, we demonstrate that a novel mesoscopic superconductivity at ambient pressure arises on the surface of MoTe2 with a critical temperature up to 5 K significantly exceeding the bulk Tc = 0.1 K. We measured the derivatives of I-V curves for hetero-contacts of MoTe 2 with Ag or Cu, homo-contacts of MoTe2 as well as "soft" point contacts (PCs). Large number of these hetero-contacts exhibit a dV/dI dependence, which is characteristic for Andreev reflection. It allows us to determine the superconducting gap Δ. The average gap values are 2Δ=1.30±0.15 meV with a 2Δ/k BTc ratio of 3.7± 0.4, which slightly exceeds the standard BCS value of 3.52. Furthermore, the temperature dependence of the gap follows a BCS-like behavior, which points to a nodeless superconducting order parameter with some strong-coupling renormalization. Remarkably, the observation of a "gapless-like" single minimum in the dV/dI of "soft" PCs may indicate a topological superconducting state of the MoTe2 surface as these contacts probe mainly the interface and avoid additional pressure effect. Therefore, MoTe2 might be a suitable material to study new forms of topological superconductivity.
ResultsPoint contact spectroscopy with "hard" tips. Figures 1 and 2 show the dV/dI curves for typical MoTe2-Ag hetero-contact (hereinafter -"hard" contact) in dependence on their temperature and in magnetic field. About a dozen of "hard" contacts with either Ag or Cu (of total 20 "hard" contacts) show similar a dV/dI dependence with a characteristic AR structure, i.e., a double-minimum around zero-bias.
We report an optimized chemical vapor transport method, which allows growing FeP single crystals up to 500 mg in mass and 80 mm 3 in volume. The high quality of the crystals obtained by this method was confirmed by means of EDX, high-resolution TEM, low-temperature single crystal XRD and neutron diffraction experiments. We investigated the transport and magnetic properties of the single crystals and calculated the electronic band structure of FeP. We show both theoretically and experimentally, that the ground state of FeP is metallic. The examination of the magnetic data reveals antiferromagnetic order below TN =119 K while transport remains metallic in both the paramagnetic and the antiferromagnetic phase. The analysis of the neutron diffraction data shows an incommensurate magnetic structure with the propagation vector Q = (0, 0, ±δ), where δ ≈ 0.2.For the full understanding of the magnetic state, further experiments are needed. The successful growth of large high-quality single crystals opens the opportunity for further investigations of itinerant magnets with incommensurate spin structures using a wide range of experimental tools.
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