Abstract.A dark region tens of kilometres wide is located in the western ablation zone of the Greenland ice sheet. The dark appearance is caused by higher amounts of dust relative to the brighter surroundings. This dust has either been deposited recently or was brought to the surface by melting of outcropping ice. Because the resulting lower albedos may have a significant effect on melt rates, we analysed surface dust on the ice, also called cryoconite, from locations in the dark region as well as locations from the brighter surrounding reference ice with microscopic and geochemical techniques to unravel its composition and origin. We find that (part of) the material is derived from the outcropping ice, and that there is little difference between dust from the dark region and from the reference ice. The dust from the dark region seems enriched in trace and minor elements that are mainly present in the current atmosphere because of anthropogenic activity. This enrichment is probably caused by higher precipitation and lower melt rates in the dark region relative to the ice marginal zone. The rare earth elemental ratios of the investigated material are approximately the same for all sites and resemble Earth's average crust composition. Therefore, the cryoconite probably does not contain volcanic material. The mineralogical composition of the dust excludes Asian deserts, which are often found as provenance for glacial dust in ice cores, as source regions. Consequently, the outcropping dust likely has a more local origin. Finally, we find cyanobacteria and algae in the cryoconite. Total Organic Carbon accounts for up to 5 weight per cent Correspondence to: I. G. M. Wientjes (i.g.m.wientjes@uu.nl) of the cryoconite from the dark region, whereas dust samples from the reference ice contain only 1 % or less. This organic material is likely formed in situ. Because of their high light absorbency, cyanobacteria and the organic material they produce contribute significantly to the low albedo of the dark region.

Abstract. The western part of the Greenland ice sheet contains a region that is darker than the surrounding ice. This feature has been analysed with the help of MODIS images.The dark region appears every year during the summer season and can always be found at the same location, which makes meltwater unlikely as the only source for the low albedos. Spectral information indicates that the ice in this region contains more debris than the ice closer to the margin. ASTER images reveal a wavy pattern in the darker ice. Based on these findings we conclude that ice, containing dust from older periods, is presently outcropping near the margin, leading to albedos lower than observed for the remaining ablation area. Therefore it can be concluded that the accumulation of meltwater is a result rather than a cause of the darkening.

A dark region in the western ablation zone of the Greenland ice sheet is caused by outcropping ice layers that contain more dust than the surrounding brighter ice. These higher amounts of dust were deposited in the accumulation zone of the ice sheet and travelled with the ice to the ablation zone. To deduce the period and the causes of this higher dust deposition, carbonaceous particles in ice samples from the dark region and from brighter reference ice were analysed and used for dating. Samples including ice from directly below the surface contain high amounts of modern organic carbon, probably from microorganisms on the ice surface. Deeper samples reveal low amounts of carbonaceous particles, which are originally deposited in the accumulation zone. The amount of outcropping carbonaceous particles in the dark region seems significantly higher than in the reference ice. One of the samples that contained material initially deposited in the accumulation zone was dated and revealed Late Holocene ages, coinciding with a period of enhanced eolian activity in the nearby tundra. Therefore, variable eolian activity during the Holocene effected dust fluxes towards the ice and hence leads to albedo variations in the present ablation zone of the ice sheet.

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A dark region of tens of kilometres width is present on the western ablation zone of the Greenland ice sheet. The dark appearance is caused by higher amounts of dust. This dust has either been deposited recently or was brought to the surface by outcropping ice. Because the resulting lower albedos may have a significant effect on melt rates, we analysed surface dust, also called cryoconite, from locations in the dark region as well as locations from the brighter surrounding reference ice with microscopic and geochemical techniques to unravel the composition and origin. We find that (part of) the material indeed crops out from the ice, and that there is little difference between dust from the dark region and from the reference ice. Although, the dust from the dark region seems enriched in trace and minor elements that are mainly present in the current atmosphere because of anthropogenic activity. This enrichment is probably caused by higher precipitation and lower melt rates in the dark region relative to the ice marginal zone. The rare earth elemental ratios of the investigated material are approximately the same for all sites and resemble Earths average crust composition. Therefore, the cryoconite does probably not contain volcanic material. The mineralogical composition of the dust excludes Asian deserts, which are often found as provenance for glacial dust in ice cores, as source regions. Consequently, the outcropping dust likely has a more regional origin. Finally, we find cyanobacteria and algae in the cryoconite. Total Organic Carbon accounts for up to 5 weight percentage of the cryoconite from the dark region, whereas dust samples from the reference ice contain only 1% or less. This organic material is likely formed in situ. Because of their high light absorbency, cyanobacteria and the organic material they produce, contribute significantly to the low albedo of the dark region