Novel fluoranthene dyes were obtained by cycloaddition reactions. The fluorescence spectra in different polar organic solvents were investigated, indicating that these dyes can be used to detect the water content in organic solvents as probes.
Self-assembly of two Zn-MOFs, [Zn2L(DMF)3]•H2O•5DMF (1) and [Zn2L(H2O)2]•4H2O•3DMF (2) were achieved with an amide-functionalized tetracarboxylate ligand under similar conditions. Incorporated amide groups make the tetratopic linkers exhibit different configurations, tetrahedron...
Solvothermal reaction of a amide-functionalized tetracarboxylate linker (H4L) with Cd(II) leads to a anionic metal-organic framework, (Me2NH2)2[Cd3(L)2]∙7H2O (1). Incorporated flexible amide group into the skeleton of H4L causes the entire...
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