A Cu-catalyzed regio- and enantioselective aminoboration of alkylidenecyclopropanes (ACPs) with bis(pinacolato)-diboron (B2pin2) and hydroxylamines has been described in this paper, affording the corresponding cyclopropane-containing β-aminoalkylboranes in good yields under mild conditions. Moreover, a catalytic asymmetric variant of this transformation has also been realized by using a copper complex with a (S)-BINAP ligand along with further transformation of the product to give cyclopropane-containing 1,2-aminoalcohols.
The use of the chiral 1,1'-binaphthyl scaffold to construct chiral ligands can be traced back for a long time. However, the development of bidentate NHC ligands based on the same backbone has only appeared recently. In this account, we describe the design and synthesis of a new family of chiral NHC ligands based on the 1,1'-binaphthyl scaffold and demonstrate the applications of these chiral NHC-metal complexes in the catalyzed oxidative kinetic resolution of secondary alcohols, asymmetric carbon-carbon bond formations, hydrosilylations, and cyclizations of 1,6-enynes. The chiral NHC ligands containing the 1,1'-binaphthyl backbone can be synthesized in good yields from enantiomerically pure 1,1'-binaphthyl-2,2'-diamine. These transition metals coordinated with chiral bidentate NHC ligands exhibit high catalytic activities and good enantioselectivities for a wide range of metal-catalyzed asymmetric reactions.
We report on a one-second-cadence wide-field survey for M-dwarf flares using the Tomo-e Gozen camera mounted on the Kiso Schmidt telescope. We detect 22 flares from M3–M5 dwarfs with a rise time of 5 s ≲ trise ≲ 100 s and an amplitude of 0.5 ≲ ΔF/F⋆ ≲ 20. The flare light-curves mostly show steeper rises and shallower decays than those obtained from the Kepler one-minute cadence data and tend to have flat peak structures. Assuming a blackbody spectrum with a temperature of 9000–15000 K, the peak luminosities and energies are estimated to be 1029 erg s−1 ≲ Lpeak ≲ 1031 erg s−1 and 1031 erg ≲ Eflare ≲ 1034 erg, which constitutes the bright end of fast optical flares for M dwarfs. We confirm that more than $90\%$ of the host stars of the detected flares are magnetically active based on their Hα-emission-line intensities obtained by LAMOST. An estimated occurrence rate of detected flares is ∼0.7 per day per active star, indicating they are common in magnetically active M dwarfs. We argue that the flare light-curves can be explained by the chromospheric compression model: the rise time is broadly consistent with the Alfvén transit time of a magnetic loop with a length scale of lloop ∼ 104 km and a field strength of 1000 gauss, while the decay time is likely determined by the radiative cooling of the compressed chromosphere down near to the photosphere with a temperature of ≳ 10000 K. These flares from M dwarfs could be a major contamination source for a future search of fast optical transients of unknown types.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.