While provision of safe drinking water is considered a basic human right, there are major challenges in the developing world for its provision. The ability to deliver safe water using a cost-appropriate technology is a major aspect of the problem. One of the technologies that has the potential to contribute significantly is the ceramic water filter (CWF); however, as shown herein, there are significant differences between performance of CWFs in the laboratory and in field applications. The CWFs employed in this study (field and laboratory) have a pore fraction of 21.0 -22.4% and an average maximum pore diameter of 5.7 -15.2 μm. Field studies were completed in Longhai City, China, a rural community in southeastern China with red earth, high precipitation and intensive human/ domestic activities. During field trials, CWFs demonstrated an average removal efficiency of 94.7%, with values ranging from 75 -100%, whereas in laboratory studies, average removal efficiency was determined to be 99.5%, with values ranging from 97.7 -99.9%. Differences between the lab and field removal efficiencies are attributed to contamination of the filter element and receptacle by villagers during field utilization and cleaning. Effective technology transfer to the end-user is required to achieve the bacterial removal efficiency attainable by the technology itself.
It is known that cell potential increases while anode resistance decreases during the start-up of microbial fuel cells (MFCs). Biological capacitance, defined as the apparent capacitance attributed to biological activity including biofilm production, plays a role in this phenomenon. In this research, electrochemical impedance spectroscopy was employed to study anode capacitance and resistance during the start-up period of MFCs so that the role of biological capacitance was revealed in electricity generation by MFCs. It was observed that the anode capacitance ranged from 3.29 to 120 mF which increased by 16.8% to 18-20 times over 10-12 days. Notably, lowering the temperature and arresting biological activity via fixation by 4% para formaldehyde resulted in the decrease of biological capacitance by 16.9 and 62.6%, indicating a negative correlation between anode capacitance and anode resistance of MFCs. Thus, biological capacitance of anode should play an important role in power generation by MFCs. We suggest that MFCs are not only biological reactors and/or electrochemical cells, but also biological capacitors, extending the vision on mechanism exploration of electron transfer, reactor structure design and electrode materials development of MFCs.
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