The intrinsic ability of cellulose nanocrystals (CNCs) to self-organize into films and bulk materials with helical order in a cholesteric liquid crystal is scientifically intriguing and potentially important for the production of renewable multifunctional materials with attractive optical properties. A major obstacle, however, has been the lack of control of helix direction, which results in a defect-rich, mosaic-like domain structure. Herein, a method for guiding the helix during film formation is introduced, which yields dramatically improved uniformity, as confirmed by using polarizing optical and scanning electron microscopy. By raising the CNC concentration in the initial suspension to the fully liquid crystalline range, a vertical helix orientation is promoted, as directed by the macroscopic phase boundaries. Further control of the helix orientation is achieved by subjecting the suspension to a circular shear flow during drying.
Carboxylated cellulose
nanofibers, prepared by TEMPO-mediated oxidation
(TOCN), were processed into asymmetric mesoporous membranes using
a facile paper-making approach and investigated as lithium ion battery
separators. Membranes made of TOCN with sodium carboxylate groups
(TOCN-COO–Na+) showed capacity fading
after a few cycles of charging and discharging. On the other hand,
its protonated counterpart (TOCN-COOH) showed highly improved electrochemical
and cycling stability, displaying 94.5% of discharge capacity maintained
after 100 cycles at 1 C rate of charging and discharging. The asymmetric
surface porosity of the membranes must be considered when assembling
a battery cell as it influences the rate capabilities of the battery.
The wood-based TOCN-membranes have a good potential as an ecofriendly
alternative to conventional fossil fuel-derived separators without
adverse side effects.
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