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The absorption coefficient of CuGeO 3 was measured in the energy range of 1-4 eV, in a temperature interval between 300 and 20 K, for light polarized along the b and c crystal axes. A weak absorption band at 1.7 eV is attributed to copper d-d transitions partially allowed by electron-phonon interactions; this is followed by a region of transparency leading to a strong exponential edge above 3 eV, which is identified with the onset of charge-transfer transitions. ͓S0163-1829͑96͒53040-7͔

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