Mn-doped ZnO multileg nanostructures were synthesized via in situ thermal oxidation of Zn and MnO2 powder. Spectroscopic measurements show that Mn ions have been doped into the lattice positions of Zn ions, which strongly induce growth of the observed ZnO multileg nanostructure. It is revealed that the growth mechanism of this kind of multileg ZnO:Mn nanostructure is different from the traditional vapor–solid or vapor–liquid–solid nucleation model of ZnO nanostructures. A possible mechanism is discussed on the basis of the growth process of a tetrapod ZnO nanostructure. Furthermore, we report the observation of an additional Raman peak. This peak is considered to have an origin related to Mn dopant in the ZnO nanostructure. This Raman feature can be regarded as an indicator for the incorporation of Mn ions into the lattice positions of the multileg ZnO nanostructure.
Amorphous ZnO granular films were fabricated by anodizing zinc sheet in 0.5M oxalic acid solution under direct current voltage. The photoluminescence spectrum of the as-anodized sample shows a very broad visible emission band, which can be Gaussian divided into two subbands at 525 and 600nm. Based on their annealing behavior and the growing mechanism of the ZnO films, the two subbands are attributed to optical transitions in oxygen vacancies and oxygen interstitials, respectively. Obvious redshifts of the two subbands were observed with increasing excitation wavelength. Spectral analyses suggest that the excitation wavelength dependences of the two subbands are due to the quantum confinement on the amorphous ZnO nanoparticles mainly with sizes of ∼10nm. This work provides a good understanding of the photoluminescence behavior of amorphous ZnO particles.
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