We calculate the effects of Pauli-blocking in the quasideuteron model of hard photon-absorption. Our approach is based upon phase space considerations and uses Fermi-gas state densities that conserve linear momentum.The Pauli-blocking function that we obtain differs from Levinger s phenomenological exponential factor and yields nuclear photoabsorption cross sections that are in good agreement with experimental data for photon energies up to the pion threshold, The temperature dependence of the nuclear photoabsorption cross section in the quasideuteron regime is also investigated. The model that we use to describe nuclear photoabsorption is particularly suited for application to preequilibrium models of hard photon emission.
Nitroethylene. -The title catalyst is successfully applied in asymmetric 1,4-addition of 3'-indolyl-3-oxidole to nitroethylene. The mixed 3,3'-bisindole products are obtained with high enantioselectivity. The non-protected and N-acyl substrates on the oxindole site do not react.The biologically important 3'-indolyl-3-pyrrolidinoindoline (IV) can be synthesized in three steps. -(AWATA, A.; WASAI, M.; MASU, H.; KADO, S.; ARAI*, T.; Chem. -Eur.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.