[1] We have developed a one-dimensional, diurnally averaged, photochemical model for Jupiter's stratosphere that couples photodissociation, chemical kinetics, vertical diffusion, and radiative transport. The predictions regarding the abundances and vertical profiles of hydrocarbon compounds are compared with observations from the Infrared Space Observatory (ISO) to better constrain the atmospheric composition, to better define the eddy diffusion coefficient profile, and to better understand the chemical reaction schemes that produce and destroy the observed constituents. From model-data comparisons we determine that the C 2 H 6 mole fraction on Jupiter is (4.0 ± 1.0) Â 10 À6 at 3.5 mbar and (2.7 ± 0.7) Â 10 À6 at 7 mbar, and the C 2 H 2 mole fraction is (1.4 ± 0.8) Â 10 À6 at 0.25 mbar and (1.5 ± 0.4) Â 10 À7 at 2 mbar. The column densities of CH 3 C 2 H and C 6 H 6 are (1.5 ± 0.4) Â 10 15 cm À2 and (8.0 ± 2) Â 10 14 cm À2 , respectively, above 30 mbar. Using identical reaction lists, we also have developed photochemical models for Saturn, Uranus, and Neptune. Although the models provide good first-order predictions of hydrocarbon abundances on the giant planets, our current chemical reaction schemes do not reproduce the relative abundances of C 2 H x hydrocarbons. Unsaturated hydrocarbons like C 2 H 4 and C 2 H 2 appear to be converted to saturated hydrocarbons like C 2 H 6 more effectively on Jupiter than on the other giant planets, more effectively than is predicted by the models. Further progress in our understanding of photochemistry at low temperatures and low pressures in hydrogen-dominated atmospheres hinges on the acquisition of high-quality kinetics data.

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Io leaves a magnetic footprint on Jupiter's upper atmosphere that appears as a spot of ultraviolet emission that remains fixed underneath Io as Jupiter rotates. The specific physical mechanisms responsible for generating those emissions are not well understood, but in general the spot seems to arise because of an electromagnetic interaction between Jupiter's magnetic field and the plasma surrounding Io, driving currents of around 1 million amperes down through Jupiter's ionosphere. The other galilean satellites may also leave footprints, and the presence or absence of such footprints should illuminate the underlying physical mechanism by revealing the strengths of the currents linking the satellites to Jupiter. Here we report persistent, faint, far-ultraviolet emission from the jovian footprints of Ganymede and Europa. We also show that Io's magnetic footprint extends well beyond the immediate vicinity of Io's flux-tube interaction with Jupiter, and much farther than predicted theoretically; the emission persists for several hours downstream. We infer from these data that Ganymede and Europa have persistent interactions with Jupiter's magnetic field despite their thin atmospheres.

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In July 2016, NASA's Juno mission becomes the first spacecraft to enter polar orbit of Jupiter and venture deep into unexplored polar territories of the magnetosphere. Focusing on these polar regions, we review current understanding of the structure and dynamics of the magnetosphere and summarize the outstanding issues. The Juno mission pro-