Inverse vulcanization is the method by which molten sulfur can be combined with comonomers to form stable polymers termed “organically modified chalcogenide” or “ORMOCHALC” polymers. One advantage to ORMOCHALC polymers is that they can possess important optical properties, such as high refractive index and strong infrared (IR) transmission, while being easier to fabricate than glass materials with similar optical properties. In the present work, a new ORMOCHALC is fabricated by using tetravinyltin as a comomoner with sulfur. This is the first example of an organometallic molecule being used as a comonomer to develop ORMOCHALCs. The result is an ORMOCHALC polymer that has the highest refractive index reported for a “sulfur and comonomer” polymer and that demonstrates unprecedented transmission in the IR region.

We demonstrate that the chalcogenide glasses possess large nonlinearities that can enable compact Raman amplifiers as well as fiber lasers and amplifiers in the mid‐IR. These high nonlinearities also allow efficient supercontinuum generation, which is useful for broadband sources in the near and mid‐IR. These materials can also be poled to induce an effective χ(2), opening up the potential of waveguide parametric amplifiers and sources. The Brillouin gain coefficients are relatively large and enable the demonstration of slow light in small core fibers. Results lead to a figure of merit that is about 140 times larger, or a theoretical gain about 45 times larger, than the best silica‐based fiber configurations reported to date.

A novel method combining elemental sulfur and selenium was developed, yielding crystalline sulfur-selenium compounds. The compounds were melted, and an organic comonomer added. Once the organic comonomer was consumed, the viscous compound was vitrified and allowed to cool yielding organic-inorganic hybrid polymers that are termed Organically Modified Chalcogenide (ORMOCHALC) polymers.

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