We have performed extensive zero field µSR experiments on pure YBa2Cu3O6+y and diluted Yrare-earth substituted Y0.92Eu0.08Ba2Cu3O6+y and Y0.925Nd0.075Ba2Cu3O6+y at light hole-doping. A common magnetic behavior is detected for all the three families, demonstrating negligible effects of the isovalent Y-substituent disorder. Two distinct regimes are identified, separated by a crossover, whose origin is attributed to the concurrent thermal activation of spin and charge degrees of freedom: a thermally activated and a re-entrant antiferromagnetic regime. The peculiar temperature and hole density dependence of the magnetic moment m(h, T ) fit a model with a (spin) activation energy for the crossover between the two regimes throughout the entire investigated range. The magnetic moment is suppressed by a simple dilution mechanism both in the re-entrant regime (0 ≤ h ≤ 0.056) and in the so-called Cluster Spin Glass state coexisting with superconductivity (0.056 < h 0.08). We argue a common magnetic ground state for these two doping regions and dub it frozen antiferromagnet. Conversely either frustration or finite-size effects prevail in the thermally activated antiferromagnetic state, that vanishes at the same concentration where superconductivity emerges, suggesting the presence of a quantum critical point at hc = 0.056(2).
An array of superconducting islands placed on a normal metal film offers a tunable realization of nanopatterned superconductivity. This system enables investigation of the nature of competing vortex states and phase transitions between them. A square array creates the eggcrate potential in which magnetic field-induced vortices are frozen into a vortex insulator. We observed a vortex insulator-vortex metal transition driven by the applied electric current and determined critical exponents that coincided with those for thermodynamic liquid-gas transition. Our findings offer a comprehensive description of dynamic critical behavior and establish a deep connection between equilibrium and nonequilibrium phase transitions.
We have used scanning micro x-ray diffraction to characterize different phases in superconducting KxFe2−ySe2 as a function of temperature, unveiling the thermal evolution across the superconducting transition temperature (Tc ∼32 K), phase separation temperature (Tps ∼520 K) and iron-vacancy order temperature (Tvo ∼580 K). In addition to the iron-vacancy ordered tetragonal magnetic phase and orthorhombic metallic minority filamentary phase, we have found a clear evidence of the interface phase with tetragonal symmetry. The metallic phase is surrounded by this interface phase below ∼300 K, and is embedded in the insulating texture. The spatial distribution of coexisting phases as a function of temperature provides a clear evidence of the formation of protected metallic percolative paths in the majority texture with large magnetic moment, required for the electronic coherence for the superconductivity. Furthermore, a clear reorganization of iron-vacancy order around the Tps and Tc is found with the interface phase being mostly associated with a different iron-vacancy configuration, that may be important for protecting the percolative superconductivity in KxFe2−ySe2.
While it is known that the nature and the arrangement of defects in complex oxides have an impact on the material functionalities, little is known about control of superconductivity by oxygen interstitial organization in cuprates. Here we report direct compelling evidence for the control of T c by manipulation of the superconducting granular networks of nanoscale puddles, made of ordered oxygen stripes, in a single crystal of YBa 2 Cu 3 O 6.5 + y with average formal hole doping p close to 1/8. Upon thermal treatments we were able to switch from a first network of oxygen defect striped puddles with OVIII modulation (q OVIII (a*) = (h + 3/8, k, 0) and q OVIII (a*) = (h + 5/8, k, 0)) to a second network characterized by OXVI modulation (q OXVI (a*) = (h + 7/16, k, 0) and qox-VI Content from this work may be used under the terms of the Creative Commons Attribution 3.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI.(a*) = (h + 9/16, k, 0)) and finally to a third network with puddles of OV periodicity (q OV (a*) = (4/10, 1, 0) and q OV (a*) = (6/10, 1, 0)). We map the microscopic spatial evolution of the out of plane OVIII, OXVI and OV puddle nanosize distribution via scanning micro-diffraction measurements. In particular, we calculated the number of oxygen chains (n) and the charge density (hole concentration p) inside each puddle, analyzing areas of 160 × 80 μm 2 , and recording 12 800 diffraction patterns to reconstruct each spatial map. The high spatial inhomogeneity shown by all the reconstructed spatial maps reflects the intrinsic granular structure that characterizes cuprates and iron chalcogenides, disclosing the presence of several complex networks of coexisting superconducting domains with different lattice modulations, charge densities and gaps as in the proposed multi-gap scenario called superstripes.
Despite intensive research a physical explanation of high Tc superconductors remains elusive. One reason for this is that these materials have generally a very complex structure making useless theoretical models for a homogeneous system. Little is known on the control of the critical temperature by the space disposition of defects because of lack of suitable experimental probes. X-ray diffraction and neutron scattering experiments used to investigate y oxygen dopants in YBa2Cu3O6+y lack of spatial resolution. Here we report the spatial imaging of dopants distribution inhomogeneity in YBa2Cu3O6.67 using scanning nano X-ray diffraction. By changing the X-ray beam size from 1 micron to 300 nm of diameter, the lattice inhomogeneity increases. The ordered oxygen puddles size distribution vary between 6–8 nm using 1 × 1 μm2 beam, while it is between 5–12 nm with a fat tail using the 300 × 300 nm2 beam. The increased inhomogeneity at the nanoscale points toward a network of superconducting puddles made of ordered oxygen interstitials.
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