Magnetic van der Waals (vdW) materials have been heavily pursued for fundamental physics as well as for device design. Despite the rapid advances, so far magnetic vdW materials are mainly insulating or semiconducting, and none of them possesses a high electronic mobilitya property that is rare in layered vdW materials in general. The realization of a magnetic high-mobility vdW material would open the possibility for novel magnetic twistronic or spintronic devices.Here we report very high carrier mobility in the layered vdW antiferromagnet GdTe 3. The electron mobility is beyond 60,000 cm 2 V -1 s -1 , which is the highest among all known layered magnetic materials, to the best of our knowledge. Among all known vdW materials, the mobility of bulk GdTe 3 is comparable to that of black phosphorus, and is only surpassed by graphite. By mechanical exfoliation, we further demonstrate that GdTe 3 can be exfoliated to ultrathin flakes of three monolayers, and that the magnetic order and relatively high mobility is retained in ~20-nm-thin flakes.VdW materials are the parent compounds of two-dimensional (2D) materials, which are currently actively studied for new device fabrications (1) involving the creation of heterostructure stacks (2) or twisted bilayers (3) of 2D building blocks. Magnetic vdW materials have recently led to the observation of intrinsic magnetic order in atomically thin layers (4-12), which was followed by exciting discoveries of giant tunneling magnetoresistance (13-16) and tunable magnetism (17)(18)(19) in such materials.So far, the known magnetic vdW materials (ferro-or antiferromagnetic) that can be exfoliated are limited to a few examples, such as: CrI3 (4), Cr2Ge2Te6 (5), FePS3 (6,7), CrBr3 (8, 9), CrCl3 (10-12), Fe3GeTe2 (17,20), and RuCl3 (21-23). Out of these, only Fe3GeTe2 is a metallic ferromagnet and there is no known vdW-based 2D antiferromagnetic metal. Moreover, no evidence of high carrier mobilities has been reported in any of these exfoliated thin materials or even in their bulk vdW crystals. In general, high mobility is limited to very few vdW materials, such as graphite (24) and black phosphorus (25). A material with high electronic mobility and a corresponding high mean-free-path (MFP), might be critical for potential magnetic "twistronic" devices (3) where a large MFP could enable interesting phenomena in a Moiré-supercell induced flat band. In addition, conducting antiferromagnetic materials are the prime candidates for high-speed antiferromagnetic spintronic devices (26). Here we report the realization of a very high electronic mobility in a vdW layered antiferromagnet, GdTe3, both in bulk and exfoliated thin flakes.We chose to study GdTe3, since rare-earth tritellurides (RTe3, R = La-Nd, Sm, and Gd-Tm) are structurally related to topological semimetal ZrSiS (27,28), while being known to exhibit an incommensurate charge density wave (CDW) (29-31), rich magnetic properties (32), and becoming superconducting under high-pressure (R = Gd, Tb and Dy) (33). Combined, these properties ...
V 2 O 3 is the prototype system for the Mott transition, one of the most fundamental phenomena of electronic correlation. Temperature, doping or pressure induce a metal-to-insulator transition (MIT) between a paramagnetic metal (PM) and a paramagnetic insulator. This or related MITs have a high technological potential, among others, for intelligent windows and field effect transistors. However the spatial scale on which such transitions develop is not known in spite of their importance for research and applications. Here we unveil for the first time the MIT in Cr-doped V 2 O 3 with submicron lateral resolution: with decreasing temperature, microscopic domains become metallic and coexist with an insulating background. This explains why the associated PM phase is actually a poor metal. The phase separation can be associated with a thermodynamic instability near the transition. This instability is reduced by pressure, that promotes a genuine Mott transition to an eventually homogeneous metallic state.
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