Interest in stratospheric aerosol and its role in climate have increased over the last decade due to the observed increase in stratospheric aerosol since 2000 and the potential for changes in the sulfur cycle induced by climate change. This review provides an overview about the advances in stratospheric aerosol research since the last comprehensive assessment of stratospheric aerosol was published in 2006. A crucial development since 2006 is the substantial improvement in the agreement between in situ and space-based inferences of stratospheric aerosol properties during volcanically quiescent periods. Furthermore, new measurement systems and techniques, both in situ and space based, have been developed for measuring physical aerosol properties with greater accuracy and for characterizing aerosol composition. However, these changes induce challenges to constructing a long-term stratospheric aerosol climatology. Currently, changes in stratospheric aerosol levels less than 20% cannot be confidently quantified. The volcanic signals tend to mask any nonvolcanically driven change, making them difficult to understand. While the role of carbonyl sulfide as a substantial and relatively constant source of stratospheric sulfur has been confirmed by new observations and model simulations, large uncertainties remain with respect to the contribution from anthropogenic sulfur dioxide emissions. New evidence has been provided that stratospheric aerosol can also contain small amounts of nonsulfate matter such as black carbon and organics. Chemistry-climate models have substantially increased in quantity and sophistication. In many models the implementation of stratospheric aerosol processes is coupled to radiation and/or stratospheric chemistry modules to account for relevant feedback processes.

Abstract. This paper presents extensive bias determination analyses of ozone observations from the Atmospheric Chemistry Experiment (ACE) satellite instruments: the ACE Fourier Transform Spectrometer (ACE-FTS) and the Measurement of Aerosol Extinction in the Stratosphere and Troposphere Retrieved by Occultation (ACE-MAESTRO) instrument. Here we compare the latest ozone data products from ACE-FTS and ACE-MAESTRO with coincident observations from nearly 20 satellite-borne, airborne, balloonborne and ground-based instruments, by analysing volume mixing ratio profiles and partial column densities. The ACE-FTS version 2.2 Ozone Update product reports more ozone than most correlative measurements from the upper troposphere to the lower mesosphere. At altitude levels from 16 to 44 km, the average values of the mean relative differences are nearly all within +1 to +8%. At higher altitudes (45-60 km), the ACE-FTS ozone amounts are significantly larger than those of the comparison instruments, with mean relative differences of up to +40% (about +20% on average). For the ACE-MAESTRO version 1.2 ozone data product, mean relative differences are within ±10% (average values within ±6%) between 18 and 40 km for both the sunrise and sunset measurements. At higher altitudes (∼35-55 km), systematic biases of opposite sign are found between the ACE-MAESTRO sunrise and sunset observations. While ozone amounts derived from the ACE-MAESTRO sunrise occultation data are often smaller than the coincident observations (with mean relative differences down to −10%), the sunset occultation profiles for ACE-MAESTRO show results that are qualitatively similar to ACE-FTS, indicating a large positive bias (mean relative differences within +10 to +30%) in the 45-55 km altitude range. In contrast, there is no significant systematic difference in bias found for the ACE-FTS sunrise and sunset measurements.

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Abstract. GOMOS on ENVISAT (launched in February, 2002) is the first space instrument dedicated to the study of the atmosphere of the Earth by the technique of stellar occultations (Global Ozone Monitoring by Occultation of Stars). Its polar orbit makes good latitude coverage possible. Because it is self-calibrating, it is particularly well adapted to long time trend monitoring of stratospheric species. With 4 spectrometers, the wavelength coverage of 248 nm to 942 nm enables monitoring ozone, H 2 O, NO 2 , NO 3 , air density, aerosol extinction, and O 2 . Two additional fast photometers (with 1 kHz sampling rate) enable the correction of the effects of scintillations, as well as the study of the structure of air density irregularities resulting from gravity waves and turbulence. A high vertical resolution profile of the temperature may also be obtained from the time delay between the red and the blue photometer. Noctilucent clouds (Polar Mesospheric Clouds, PMC) are routinely observed in both polar summers and global observations of OClO and sodium are achieved.The instrument configuration, dictated by the scientific objectives' rationale and technical constraints, is described, together with the typical operations along one orbit, along with the statistics from over 6 years of operation. Typical atmospheric transmission spectra are presented and some retrieval difficulties are discussed, in particular for O 2 and H 2 O.Correspondence to: J. L. Bertaux (bertaux@latmos.ipsl.fr) An overview is presented of a number of scientific results already published or found in more detail as companion papers in the same ACP GOMOS special issue. This paper is particularly intended to provide an incentive for the exploitation of GOMOS data available to the whole scientific community in the ESA data archive, and to help GOMOS data users to better understand the instrument, its capabilities and the quality of its measurements, thus leading to an increase in the scientific return.

[1] The Global Ozone Monitoring by Occultation of Stars (GOMOS) instrument on board the European Space Agency's Envisat satellite measures ozone and a few other trace gases using the stellar occultation method. Global coverage, good vertical resolution and the self-calibrating measurement method make GOMOS observations a promising data set for building various climatologies. In this paper we present the nighttime stratospheric ozone distribution measured by GOMOS in 2003. We show monthly latitudinal distributions of the ozone number density and mixing ratio profiles, as well as the seasonal variations of profiles at several latitudes. The stratospheric profiles are compared with the Fortuin-Kelder daytime ozone climatology. Large differences are found in polar areas and they can be shown to be correlated with large increases of NO 2 . In the upper stratosphere, ozone values from GOMOS are systematically larger than in the Fortuin-Kelder climatology, which can be explained by the diurnal variation. In the middle and lower stratosphere, GOMOS finds a few percent less ozone than Fortuin-Kelder. In the equatorial area, at heights of around 15-22 km, GOMOS finds much less ozone than Fortuin-Kelder. For the mesosphere and lower thermosphere, there has previously been no comprehensive nighttime ozone climatology. GOMOS is one of the first new instruments able to contribute to such a climatology. We concentrate on the characterization of the ozone distribution in this region. The monthly latitudinal and seasonal distributions of ozone profiles in this altitude region are shown. The altitude of the mesospheric ozone peak and the semiannual oscillation of the number density are determined. GOMOS is also able to determine the magnitude of the ozone minimum around 80 km. The lowest seasonal mean mixing ratio values are around 0.13 ppm. The faint tertiary ozone peak at 72 km in polar regions during wintertime is observed.