The reaction of a copper complex bearing iminosemiquinone ligands with a CF3(+) source provides an unprecedented Cu(II)-CF3 complex through ligand-based oxidation. Reactivity of this complex leads to nucleophilic trifluoromethylation of the ligand, suggesting an electronic interplay that results in a formal umpolung of the initial CF3(+).
A series of new secondary phosphine
oxide (SPO)–gold(I)
complexes have been synthesized and characterized by X-ray crystallography.
Complexes exhibited dimeric structures interconnected by O–H···Cl
hydrogen bonds. Their first use in homogeneous catalysis is reported
and suggests a broad field of application in prototypical enyne cycloisomerization
and hydroxy- and methoxycyclization reactions.
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