Development of lightweight core sandwich based bioresin for ship structure application needs more attention. Bioresin from vegetable oils constitutes single, easily available, low cost, and biodegradable materials. In this research, the vinyl ester bioresin based Vinyl Ester-Coconut Oil (VE-CO) and Vinyl Esters-Soybean Oil (VE-SbO) containing 4 wt% vegetable oils are developed. The influence of vegetable oil addition in bioresin is characterized by visual observation and physical testing, including FTIR, density, hardness, and tensile test based on Lloyds Register standard. Visual testing shows that VE without vegetable oil is more transparent compared with VE with vegetable oil. The density test shows that adding vegetable oil decrease the apparent density. Vibration pattern indicates the presence of O-H, C-H, C=O, C=C, and C-O-C, which demonstrate the ability to bind, which leads to the potential formation of a polymer blend and elongation increase. Moreover, hardness decreases due to the absence of chemical bonds that occur between vinyl esters and vegetable oils. The addition of vegetable oil to vinyl ester bioresin reduces tensile strength and increases the elongation at break. So, density and tensile strength criteria meet Lloyd’s Register Standard while the other criteria are not fulfilled.
Abstract.This research studied the inhibition of corrosion by bawang dayak leaves extract (EleutherineamericanaMerr.) on API 5L steel in brine water environment (3.5% NaCl). The inhibitor was extracted using maceration process from bawang dayak leaves that was cultivated in Paser District, East Kalimantan. The test of antioxidant activity showed that bawang dayak leaves extract is a very powerful antioxidant with IC 50 value of 27.30204. The results from FTIR test show the presence of electronegative atoms and double bonds of the alkenes groups that provide the potential of the extract as a corrosion inhibitor. Efficiency of inhibition reached up to 93.158% for the addition of inhibitor with 300 ppm concentration and 20 days of immersion time. This inhibitory behavior is also supported by polarization measurements where the lowest corrosion rate of 0.00128 mm/year is obtained at the same concentration and immersion time.
Vegetable oil is biodegradable, non-toxic, environmentally friendly, and renewable so that it becomes an alternative to replace mineral oil and chemicals. This research will develop a bioresin which is a mixture of epoxy with natural polymer such as palm oil. The homogenization method uses a hot plate so that the mixing reaches miscible materials. The results of bioresin testing with variations in the composition of palm oil showed that the optimal composition variation was E-MS (10%) because it had a low tensile strength value of 53.111Mpa. While the highest elongation value is 14.04767%, and has a low hardness value of 86.3 on the shore D scale. The highest density value is 1.25254(g/cm3). Judging from the standard L'loyd Register and BKI (Indonesian Classification Agency) that the values of all tensile strength test results meet the standards and all variations in the composition of the test results and elongation values meet the minimum criteria.
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