A phenomenological theory of direct current across the metal–solid electrolyte interface is presented, using the assumption that cations are the only mobile charge carriers in the electrolyte. The current–voltage characteristic of the system is obtained under the assumption that a delayed stage of the electrode reaction is the electron transfer in cation discharge or ionization of metal ions.
Under study were the UV and PMR spectra as well as the electron structure of 4-alky1, 4-alkoxy-4-cyanobiphenyls, 6-p-alkylphenyl-, 6-p-alkoxyphenyl-3-cyanopyridines and 5-alkyl-2-p-cyanophenylpyridines in the ground and first excited states. To study these compounds a quantitative method is offered for determination the rotation angle between the planes of bicyclic molecular fragments based on the excitation theory within the frames of the Hiickel technique and on the UV spectroscopy data.
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