The simulation of fermionic systems is among the most anticipated applications of quantum computing. We performed several quantum simulations of chemistry with up to one dozen qubits, including modeling the isomerization mechanism of diazene. We also demonstrated error-mitigation strategies based on N-representability that dramatically improve the effective fidelity of our experiments. Our parameterized ansatz circuits realized the Givens rotation approach to noninteracting fermion evolution, which we variationally optimized to prepare the Hartree-Fock wave function. This ubiquitous algorithmic primitive is classically tractable to simulate yet still generates highly entangled states over the computational basis, which allowed us to assess the performance of our hardware and establish a foundation for scaling up correlated quantum chemistry simulations.
We show that, by treating the gravitational interaction between two mechanical resonators as a classical measurement channel, a gravitational decoherence model results that is equivalent to a model first proposed by Diosi. The resulting decoherence model implies that the classically mediated gravitational interaction between two gravitationally coupled resonators cannot create entanglement. The gravitational decoherence rate (and the complementary heating rate) is of the order of the gravitationally induced normal mode splitting of the two resonators. Failure to see this in an experiment would rule out treating gravitational interactions as purely classical.
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