Small additions of nanofiber materials make it possible to change the properties of polymers. However, the uniformity of the additive distribution and the strength of its bond with the polymer matrix are determined by the surface of the nanofibers. Silanes, in particular, allow you to customize the surface for better interaction with the matrix. The aim of our work is to study an approach to silanization of nanofibers of aluminum oxide to obtain a perfect interface between the additive and the matrix. The presence of target silanes on the surface of nanofibers was shown by XPS methods. The presence of functional groups on the surface of nanofibers was also shown by the methods of simultaneous thermal analysis, and the stoichiometry of functional groups with respect to the initial hydroxyl groups was studied. The number of functional groups precipitated from silanes is close to the number of the initial hydroxyl groups, which indicates a high uniformity of the coating in the proposed method of silanization. The presented technology for silanizing alumina nanofibers is an important approach to the subsequent use of this additive in various polymer matrices.
The paper deals with the production and study of nanocomposite powder paints based on alumina nanofibers. For nanodispersed fillers, the nature of the surface states on the filler particles is important. The problem of introducing nanomaterials into a polymer matrix cannot provide an effective solution without matching the surface states of the nanomaterial filler and the polymer matrix for the resulting composite materials. The consistency of the surface states of the nanomaterial filler and the polymer matrix determines the quality of transfer of the necessary properties to the resulting polymer composite. In order to increase the affinity of alumina nanofibers with a matrix of powder paint, the nanofibers were treated with 3-glycidyloxypropyltrimethoxysilane (GLYMO) in toluene. It is shown in the work that the addition of alumina nanofibers leads to a hardening of the coating, an increase in its elasticity, and an increase in corrosion resistance. Finishing of alumina nanofibers in a solution of silane in toluene leads to its functionalization, which is sufficient for the distribution of nanofibers in the polymer matrix of the paint and improvement of its operational properties.
The paper describes the effect of the addition of alumina nanofibers on the mechanical properties of the epoxy resin. Alumina nanofibers functionalized with epoxypropyl functional groups are used in this work. The dependence of the mechanical characteristics on the amount of the additive, as well as the features of its distribution in the material, is investigated. In the work, nanocomposites were obtained, which are epoxy resin with aluminum oxide nanofibers. The mechanical properties of the samples were studied by bending tests and differential mechanical analysis (DMA). It has been shown that the addition of alumina nanofibers leads to an increase in ultimate flexural strength. The maximum of this increase is near the percolation threshold of alumina nanofibers in epoxy resin. With the addition of 0.2% alumina nanofibers, the ultimate flexural strength increases from 41 to 71 MPa. It is shown that after exceeding the percolation threshold of nanofibers, the ultimate strength decreases. In this case, the elastic modulus increases from 0.643 to 0.862 GPa. DMA is shown that the glass transition temperature decreases with increasing amount of the additive. This indicates a decrease in the molecular weight of the polymer. By implication, this suggests that the hardener connects the epoxypropyl functional groups on the nanofibers and the epoxy groups in the resin, and as a result of this process, the nanofibers become natural polymer chain length limiters. The data obtained from mechanical testing and differential mechanical analysis can be used to strengthen epoxy resins in polymer composite materials and molding compositions.
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