Versión / Versió:Pre-print Cita bibliográfica / Cita bibliogràfica (ISO 690):GONZÁLEZ-PEDRO, Victoria, et al. High performance PbS Quantum Dot Sensitized Solar Cells exceeding 4% efficiency: the role of metal precursors in the electron injection and charge separation. Physical Chemistry Chemical Physics, 2013, vol. 15, no 33, p. 13835-13843.

Hydrogen generation by using quantum dot based heterostructures has emerged as a promising strategy to develop artificial photosynthesis devices. In the present study, we sensitize mesoporous TiO 2 electrodes with in-situ deposited PbS/CdS quantum dots (QDs), aiming at harvesting light in both the visible and the near infrared for hydrogen generation. This heterostructure exhibits a remarkable photocurrent of 6 mA·cm -2 leading to 60 ml·cm -2 ·day -1 hydrogen generation. Most importantly, confirmation of the contribution of infrared photons to H 2 generation was provided by the incident-photon-to-current-efficiency (IPCE), and the integrated current was in excellent agreement with that obtained through cyclic voltammetry.The main electronic processes (accumulation, transport and recombination) were identified by impedance spectroscopy, which appears as a simple and reliable methodology to evaluate the limiting factors of these photoelectrodes. Based on this TiO 2 /PbS/CdS heterostructrure, a "quasiartificial leaf" has been developed, which has proven to produce hydrogen under simulated solar illumination at (4.30 ± 0.25) ml·cm -2 ·day -1 .