Two acetylene-bridged molecules, built by grafting phthalimides on thienoisoindigo (TII) and diketopyrrolopyrrole (DPP) blocks, have been synthesized, characterized and evaluated as electron acceptor materials in air-processed inverted organic solar cells.
New
three-dimensional hole-transporting materials (HTMs) based
on either 9,9′-spirobifluorene (SBF) or spiro-[cyclopenta[1,2-b:5,4-b′]dithiophene-4,9′-fluorene]
(SDTF) core have been synthesized. All three HTMs, namely, SBFCz2, SDTFCz2, and SDTCz2F, are end-capped
with two peripheral 3,6-dimethoxydiphenylaminyl-carbazole (CzDMPA)
units. The HTMs behave as molecular glasses with glass transition
temperature (T
g) close to or higher than
that of the reference HTM Spiro-OMeTAD. Thermal and optoelectronic
properties strongly depend upon the nature of the bridging core unit
between the two CzDMPA units. The two fluorene-bridged molecules SBFCz2 and SDTFCz2 exhibit similar properties.
On the contrary, SDTCz2F, where the CzDMPA units are
bridged to the cyclopentadithiophene ring, displays lower highest
occupied molecular orbital/lowest unoccupied molecular orbital energy
levels and smaller band gaps. Upon doping of the HTM layer in perovskite
solar cells, in spite of a much lower hole mobility, SDTCz2F leads to the highest power conversion efficiency (16.4% compared
to 14.5 and 14.3% for SBFCz2 and SDTFCz2, respectively).
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.