Design and fabrication of freestanding chiro‐photonic crystal film with the ability to change color over the whole visible light spectrum is appealing for anticounterfeiting technology and smart labels. Utilizing a newly synthesized light‐responsive molecular motor functionalized with cholesterol (chol‐MM) on the rotor, novel light‐controlled photonic crystal is prepared by doping the novel chol‐MM into liquid crystals (LCs). Thanks to the liquid crystalline cholesterol substituent, the chol‐MM can be triggered by visible light (420 nm). At the same time, the miscibility of chol‐MM in LC matrix is significantly enhanced. Integrating the chol‐MM with thermochromic hydrogen‐bonded LC matrix, thermal and light dual‐responsive cholesteric LC (CLC) material is prepared, in which the nanoscale helical pitch is tunable by photo‐induced molecular motions of chol‐MM. More importantly, utilizing UV‐initiated polymerization of the visible light‐modulated CLC material, structural colored photonic crystal films with arbitrary colorful patterns are fabricated. Such freestanding helical nanostructured labels have potential in the application of encrypted communication and anticounterfeiting.
Design and fabrication of advanced security label showing superior performance in data encryption has attracted tremendous scientific interests. Especially, multifunctional optical labels capable of storing distinct information in different modes are highly demanded.Here, a fluorescent cholesteric liquid crystalline network (CLCN) film with programmable visible patterns and photo-rewritable fluorescent patterns was designed and prepared. The visible patterns were fixed by helical network and the colors of visible patterns were tunable by changing relative humidity (RH). The fluorescent patterns originated from dynamic isomerization of fluorescent hydrazones, exhibiting highly thermal stability and switching-ability controlled by light. The orthogonal construction of visible and fluorescent pattern enabled the novel CLCN to encrypt distinct information in reflective mode and in emissive mode, indicating its potential in anti-counterfeiting and information encryptions.
Liquid
crystalline polymer (LCP) is a promising candidate in the
design and fabrication of intelligent soft materials due to the combination
of programmable anisotropy and elasticity. Here, a novel strategy
to fabricate reprogrammable humidity-responsive LCP materials enabled
by dynamic ionic cross-links were put forward. The prepared LCP film
deforms reversibly with the change of relative humidity (RH). However,
the humidity responsivity loses after soaking the film into CaCl2 solution because of the lock of hygroscopic groups by the
formed ionic bonds. By selectively cross-linking specific regions
of the LCP film, distinctive humidity-driven motions of the film could
be realized. More interestingly, by the EDTA-2K solution treatment,
ionic cross-links can be interrupted, leading the LCP film responsive
to humidity again. Thanks to feasibly removable ionic cross-links,
the humidity-directed soft actuator was totally reprogrammable. The
behavior of the novel actuator could be manipulated by either the
mesogens alignment or the spatially ionic treatment, providing a feasible
but robust strategy to fabricate complex humidity-driven soft robots.
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