Extraction of La(iii), Eu(iii) and Fe(iii) was compared in n-dodecane and in two ionic liquids (ILs) [EBPip+] [NTf2−] and [EOPip+] [NTf2−]. Extraction mechanisms have been investigated as a function of pH.
This work attempts to study the interaction of two ionic liquids (1-ethyl-3-methylimidazolium tosylate and 1-hexyl-3-methylimidazolium chloride) with chemically crosslinked poly(N-vinylimidazole) in aqueous media, and to compare it with that of NaCl, a typical salting-out electrolyte. The three salts show a salting-in effect whose intensity was measured on the basis of the decrease of the polymer-solvent interaction parameter and the increase of swelling with increasing ionic strength. It was thus found that the salting-in effect is the same for the two salts with the same anion (chloride), while the intensity of the salting-in effect exerted by the tosylate ionic liquid is larger. The coefficient of selective sorption, which expresses the salt excess inside the swollen gel with respect to the external solution was determined by comparing the initial and equilibrium compositions of the immersion bath. These results are discussed in terms of the hydrophobic character of the ions involved.
The lyotropic behavior of the ternary system formed by 1-tetradecyl-3-methylimidazolium chloride, 1-decanol, and water is investigated. A lamellar mesophase is formed for a wide range of compositions and is characterized by polarized optical microscopy, low-temperature scanning electron microscopy, small- and wide-angle X-ray scattering with synchrotron radiation, and differential scanning calorimetry. This phase presents onionlike structures. Two lamellar structures are formed: an L mesophase between 25 and 50 °C, with an isobaric thermal expansivity of the bilayer thickness of -3.2 × 10 K, and a lamellar gel phase, when the temperature decreases below 25 °C. This new medium is employed to perform in situ X-ray-initiated polymerization of N-isopropylacrylamide. When the monomer is incorporated in the lamellar structure, it is distributed between the water layer and bilayer interface and its polymerization can be followed by variations in the diffractograms with time.
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