Almost all surfaces sensitive to the ambient environment are covered by water, whereas the impacts of water on surface-dominated colloidal quantum dot (CQD) semiconductor electronics have rarely been explored. Here, strongly hydrogen-bonded water on hydroxylated lead sulfide (PbS) CQD is identified. The water could pilot the thermally induced evolution of surface chemical environment, which significantly influences the nanostructures, carrier dynamics, and trap behaviors in CQD solar cells. The aggravation of surface hydroxylation and water adsorption triggers epitaxial CQD fusion during device fabrication under humid ambient, giving rise to the inter-band traps and deficiency in solar cells. To address this problem, meniscus-guided-coating technique is introduced to achieve dense-packed CQD solids and extrude ambient water, improving device performance and thermal stability. Our works not only elucidate the water involved PbS CQD surface chemistry, but may also achieve a comprehensive understanding of the impact of ambient water on CQD based electronics.
Balanced charge injection is key to achieving perovskite light-emitting diodes (PeLEDs) with a low efficiency roll-off at a high brightness. The use of zinc oxide (ZnO) with a high electron mobility as the charge transport layers is desirable; however, photoluminescence (PL) quenching of a perovskite on ZnO always occurs. Here, a quasitwo-dimensional perovskite on ZnO is explored to uncover the PL quenching mechanism, mainly ascribed to the deprotonation of ammonium cations on the ZnO film in association with the decomposition of low-dimensional perovskite phases. Surprisingly, crystal planedependent PL quenching results indicate that the deprotonation rate strongly correlates with the crystal orientation of the ZnO surface. We developed a strategy for suppressing perovskite PL quenching by incorporating an atomic layer deposited Al 2 O 3 onto the ZnO film. Consequently, an efficient inverted PeLED was achieved with a maximum external quantum efficiency of 17.7% and a less discernible efficiency roll-off at a high current density.
The energy-level alignment at hybrid organic-inorganic interfaces is decisive for the performance of (opto-)electronic devices. We use ultraviolet and X-ray photoelectron spectroscopy (UPS and XPS) to measure the energy-level alignment of vacuum-sublimed -sexithiophene (6T) thin films with HF-etched n-type Si(100) and with Si with a native oxide layer (SiOx). The 6T thin films induce a small (<0.1 eV) downwards band bending into both substrates as shown by XPS. The well-ordered growth of 6T on Si leads to a relatively narrow density of states (DOS) distribution of the highest occupied molecular orbital (HOMO) as shown by UPS. Furthermore, the Fermi-level comes to lie at rather mid-gap position and, consequently, no energy-level bending occurs in the 6T layer. Structural disorder in the 6T thin film on SiOx leads to a broad HOMO DOS distribution and to tailing states into the energy gap. Consequently, downwards energy-level bending (by around 0.20 eV) takes place in the 6T layer.
Soil treated with silicone hydrophobic material for a long time can effectively improve the saturated permeability of the ground, which has been confirmed. However, the long time will increase the cost in engineering construction. Secondly, the mechanism of alteration of soil–water properties by silicone hydrophobic materials is not understood. This lack of understanding is not conducive to the engineering application of silicone hydrophobic materials. Therefore, variable-head permeability and matrix suction tests under 15 different test conditions were conducted with different hydrophobic material dosage and action time as variables in this paper. The soil–water characteristic curve (SWCC) was plotted according to the test results, the unsaturated permeability coefficient was calculated, and curve fitting was performed. It can be seen from the test data that, with the increase in the dosage of hydrophobic materials and the action time, the permeability coefficient and the air-entry value showed a downward trend. Nevertheless, as the reaction proceeded, a mutation occurred at 4 h. When the minimum dosage and action time were used, the soil’s permeability coefficient and air-entry value decreased by 80.65% and 71.09%. The test results show that, even when the action time was 2 h, the hydrophobic material could maintain the permeability of the soil and reduce its air-entry value; thus, the hydrophobic material could effectively reduce the rise of capillary water in the soil and protect the roadbed.
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