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Gadolinium-Doped Ceria (GDC) is a prospective material for application in electrochemical devices. Free sintering in air of GDC powder usually requires temperatures in the range of 1400 to 1600 °C and dwell time of several hours. Recently, it was demonstrated that sintering temperature can be significantly decreased, when sintering was performed in reducing atmosphere. Following re-oxidation at elevated temperatures was found to be a helpful measure to avoid sample failure. Sintering temperature and dwell time can be also decreased by use of Spark Plasma Sintering, also known as Field-Assisted Sintering Technique (FAST/SPS). In the present work, we combined for the first time the advantages of FAST/SPS technology and re-oxidation for sintering of GDC parts. However, GDC samples sintered by FAST/SPS were highly sensitive to fragmentation. Therefore, we investigated the factors responsible for this effect. Based on understanding of these factors, a special tool was designed enabling pressureless FAST/SPS sintering in controlled atmosphere. For proof of concept, a commercial GDC powder was sintered in this tool in reducing atmosphere (Ar-2.9%H2), followed by re-oxidation. The fragmentation of GDC samples was avoided and the number of micro-cracks was reduced to a minimum. Prospects of GDC sintering by FAST/SPS were discussed.

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The microstructure and mechanical properties of high‐speed steel AISI M50 (80MoCrV42‐16, Mat. Nr. 1.3551), produced by laser powder bed fusion (LPBF), are analyzed. The mechanical properties in hardened and tempered condition are characterized by hardness, fatigue strength, and toughness and compared with the properties of conventionally produced samples. Moreover, the effects of an additional posttreatment by hot isostatic pressing (HIP) on the microstructure and mechanical properties are investigated. Dilatometric testing is used to investigate the influence of the different initial microstructures on hardening. All heat‐treated samples expose a fine martensitic microstructure with high hardness. The conventionally produced samples show a band‐like orientation of carbides due to the production by vacuum induction melting and vacuum arc remelting followed by a hot working process. This carbide structure is bypassed by the rapid cooling in the LPBF process. The LPBF samples show a comparable hardness after hardening and tempering to the conventionally produced material. In heat‐treated state, the LPBF samples show a low fatigue strength. Posttreatment by HIP included in the heat‐treatment chain significantly increases the fatigue strength. Nevertheless, the fatigue strength is still lower compared with the reference material. Both LPBF grades show a low toughness compared with the reference material.

In the last years, a lot of ceramic materials were developed that, at higher temperatures, have a high electrical conductivity and a high conductivity of oxygen ions. Such mixed ionic/electronic conductors can be used to produce high‐purity oxygen. This work focuses on the realization of a pilot membrane module, with BSCF (Ba0.5Sr0.5Co0.8Fe0.2O3‐δ) perovskite selected as the membrane material. An amount of 500 kg of powder was industrially fabricated, spray‐granulized and pressed into tubes. The best operation conditions concerning energy consumption were calculated, and a module reactor was designed operating at 850 °C, with an air pressure of 15–20 bar on the feed site and a low vacuum of about 0.8 bar on the permeate site. Special emphasis was placed on joining alternatives for ceramic tubes in metallic bottoms. A first laboratory module was tested with a membrane area of 1 m2 and then advanced to a pilot module with 570 tubes and a capability of more than 300 000 L of pure oxygen per day.