The ligand functionalization effect on the CO(2)/CH(4) separation performance of the MOF type UiO-66(Zr) was explored computationally. The -SO(3)H and -CO(2)H functionalized forms show the highest selectivity, good working capacity and medium ranged CO(2) adsorption enthalpy that make these materials very promising for physisorption-based processes.
The present study illustrates the importance of the oxidation state of iron within the mesoporous iron trimesate [{Fe(3)O(H(2)O)(2)F(0.81)(OH)(0.19)}{C(6)H(3)(CO(2))(3)}(2)] denoted MIL-100(Fe) (MIL= Material from Institut Lavoisier) during adsorption of molecules that can interact with the accessible metal sites through π-back donation. Adsorption of CO has been first followed by FTIR spectroscopy to quantify the Lewis acid sites in the dehydrated Fe(III) sample, outgassed at 150 °C, and on the partially reduced Fe(II/III), outgassed at 250 °C. The exposure of MIL-100(Fe) to CO(2), propane, propene and propyne has then been studied by FTIR spectroscopy and microcalorimetry. It appears that π-back donating molecules are strongly adsorbed on reduced iron(II) sites despite the weaker Lewis acidity of cus Fe(2+) sites compared to that of Fe(3+) ones, as shown by pyridine adsorption.
In addition to its high thermal stability, repetitive hydration/dehydration tests have revealed that the porous zirconium terephthalate UiO-66 switches reversibly between its dehydroxylated and hydroxylated versions. The structure of its dehydroxylated form has thus been elucidated by coupling molecular simulations and X-ray powder diffraction data. Infrared measurements have shown that relatively weak acid sites are available while microcalorimetry combined with Monte Carlo simulations emphasize moderate interactions between the UiO-66 surface and a wide range of guest molecules including CH(4), CO, and CO(2). These properties, in conjunction with its significant adsorption capacity, make UiO-66 of interest for its further evaluation for CO(2) recovery in industrial applications. This global approach suggests a strategy for the evaluation of metal-organic frameworks for gas-based applications.
International audienceA combination of experimental (gravimetry, microcalorimetry, and quasi-elastic neutron scattering) measurements and molecular modeling was employed to understand the coadsorption of CO2 and CH4 in the zirconium terephthalate UiO-66(Zr) material from both the thermodynamic and kinetic points of view. It was shown that each type of molecules adsorb preferentially in two different porosities of the material, that is, while CO2 occupy the tetrahedral cages, CH4 are pushed to the octahedral cages. Further, a very unusual dynamic behavior was also pointed out with the slower molecule, that is, CO2, enhancing the mobility of the fast one, that is, CH4, that contrasts with those usually observed so far for the CO2/CH4 mixture in narrow window zeolites where the molecules are most commonly diffusing independently or slowing-down the partner species. Such behavior was interpreted in light of molecular simulations that evidenced a jump type mechanism involving a tetrahedral cages-octahedral cages-tetrahedral cages sequence that occurs more frequently for CH4 when in presence of CO2. The consequences in terms of CO2/CH4 selectivity and the possible use of this MOF-type material in a PSA process are then discussed. It is thus clearly emphasized that this MOF material combines several favorable features including a good selectivity, high working capacity, and potential easy regenerability that make it as a good alternative candidate of the conventional NaX Faujasite used in pressure swing adsorption
One flue over the cuckoo's nest: A novel porous Zr‐based MOF combining a high chemical stability, easy “green” synthesis and scalability is prepared. This material incorporating carboxylic functions on its organic linkers has thermodynamically and kinetically very promising properties for CO2 capture from post‐combustion flue gas under real working conditions.
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