Rayleigh–Bénard convection in water is studied by means of direct numerical simulations, taking into account the variation of properties. The simulations considered a three-dimensional (3-D) cavity with a square cross-section and its two-dimensional (2-D) equivalent, covering a Rayleigh number range of $10^{6}\leqslant Ra\leqslant 10^{9}$ and using temperature differences up to 60 K. The main objectives of this study are (i) to investigate and report differences obtained by 2-D and 3-D simulations and (ii) to provide a first appreciation of the non-Oberbeck–Boussinesq (NOB) effects on the near-wall time-averaged and root-mean-squared (r.m.s.) temperature fields. The Nusselt number and the thermal boundary layer thickness exhibit the most pronounced differences when calculated in two dimensions and three dimensions, even though the $Ra$ scaling exponents are similar. These differences are closely related to the modification of the large-scale circulation pattern and become less pronounced when the NOB values are normalised with the respective Oberbeck–Boussinesq (OB) values. It is also demonstrated that NOB effects modify the near-wall temperature statistics, promoting the breaking of the top–bottom symmetry which characterises the OB approximation. The most prominent NOB effect in the near-wall region is the modification of the maximum r.m.s. values of temperature, which are found to increase at the top and decrease at the bottom of the cavity.
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