The NERC and CEH trademarks and logos ('the Trademarks') are registered trademarks of NERC in the UK and other countries, and may not be used without the prior written consent of the Trademark owner.

Abstract. High-frequency, long-term and multisolute measurements are required to assess the impact of human pressures on water quality due to (i) the high temporal and spatial variability of climate and human activity and (ii) the fact that chemical solutes combine short-and long-term dynamics. Such data series are scarce. This study, based on an original and unpublished time series from the Kervidy-Naizin headwater catchment (Brittany, France), aims to determine solute transfer processes and dynamics that characterise this strongly human-impacted catchment.The Kervidy-Naizin catchment is a temperate, intensive agricultural catchment, hydrologically controlled by shallow groundwater. Over 10 yr, five solutes (nitrate, sulphate, chloride, and dissolved organic and inorganic carbon) were monitored daily at the catchment outlet and roughly every four months in the shallow groundwater.The concentrations of all five solutes showed seasonal variations but the patterns of the variations differed from one solute to another. Nitrate and chloride exhibit rather smooth variations. In contrast, sulphate as well as organic and inorganic carbon is dominated by flood flushes. The observed nitrate and chloride patterns are typical of an intensive agricultural catchment hydrologically controlled by shallow groundwater. Nitrate and chloride originating mainly from organic fertilisers accumulated over several years in the shallow groundwater. They are seasonally exported when upland groundwater connects with the stream during the wet season. Conversely, sulphate as well as organic and inorganic carbon patterns are not specific to agricultural catchments. These solutes do not come from fertilisers and do not accumulate in soil or shallow groundwater; instead, they are biogeochemically produced in the catchment. The results allowed development of a generic classification system based on the specific temporal patterns and source locations of each solute. It also considers the stocking period and the dominant process that limits transport to the stream, i.e. the connectivity of the stocking compartment. This mechanistic classification can be applied to any chemical solute to help assess its origin, storage or production location and transfer mechanism in similar catchments.

Multi-Criteria Decision Analysis (MCDA) needs tools to enable citizen participation 43 reviewed water-related serious games reveal diverse approaches and uses Serious games in MCDA entail communicating about and with models (behavioral OR) No existing serious game allows MCDA-compatible preference elicitation

Recently developed measurement technologies can monitor surface water quality almost continuously, creating high-frequency multiparameter time series and raising the question of how best to extract insights from such rich data sets. Here we use spectral analysis to characterize the variability of water quality at the AgrHys observatory (Western France) over time scales ranging from 20 min to 12 years. Three years of daily sampling at the intensively farmed Kervidy-Naizin watershed reveal universal 1/f scaling for all 36 solutes, yielding spectral slopes of 1.05 ± 0.11 (mean ± standard deviation). These 36 solute concentrations show varying degrees of annual cycling, suggesting different controls on watershed export processes. Twelve years of daily samples of SO4, NO3, and dissolved organic carbon (DOC) show that 1/f scaling does not continue at frequencies below 1/year in those constituents, whereas a 12-year daily record of Cl shows a general 1/f trend down to the lowest measurable frequencies. Conversely, approximately 12 months of 20 min NO3 and DOC measurements show that at frequencies higher than 1/day, the spectra of these solutes steepen to slopes of roughly 3, and at time scales shorter than 2-3 h, the spectra flatten to slopes near zero, reflecting analytical noise. These results confirm and extend the recent discovery of universal fractal 1/f scaling in water quality at the relatively pristine Plynlimon watershed in Wales, further demonstrating the importance of advective-dispersive transport mixing in catchments. However, the steeper scaling at subdaily time scales suggests additional short-term damping of solute concentrations, potentially due to in-stream or riparian processes.