Berkelium is positioned at a crucial location in the actinide series between the inherently stable half-filled 5f(7) configuration of curium and the abrupt transition in chemical behavior created by the onset of a metastable divalent state that starts at californium. However, the mere 320-day half-life of berkelium's only available isotope, (249)Bk, has hindered in-depth studies of the element's coordination chemistry. Herein, we report the synthesis and detailed solid-state and solution-phase characterization of a berkelium coordination complex, Bk(III)tris(dipicolinate), as well as a chemically distinct Bk(III) borate material for comparison. We demonstrate that berkelium's complexation is analogous to that of californium. However, from a range of spectroscopic techniques and quantum mechanical calculations, it is clear that spin-orbit coupling contributes significantly to berkelium's multiconfigurational ground state.

The internal-conversion and internal-pair-production decays of the first excited 0 + state in 68 Ni are studied following the β decay of 68 Co. A novel experimental technique, in which the ions of 68 Co were implanted into a planar germanium double-sided strip detector and which required digital pulse processing, is developed. The values for the energy of the first excited 0 + state and the electric monopole transition strength from the first excited 0 + state to the ground state in 68 Ni are determined to be 1605(3) keV and 7.6(4) × 10 −3 , respectively. Comparisons of the experimental results to Monte Carlo shell-model calculations suggest the coexistence between a spherical ground state and an oblate first excited 0 + state in 68 Ni.

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