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Despite a number of published papers focusing on the geodynamic implications of the recent Southern Puna mafic magmatism, there have been fewer studies of the volcanology and stratigraphy of this outstanding volcanism. This paper presents a detailed map of two wellpreserved Quaternary scoria cones showing their complex stratigraphy. Complementary morphometric, morpho-structural, petrographic and geochemical data were used to reconstruct the evolution of both volcanoes. The occurrence of more than one eruption at each volcano was inferred by the recognition of temporal hiatuses using morpho-stratigraphic criteria. The polycyclic nature of both scoria cones could be related to a combination of a high input magma in response to lithospheric delamination, a favourable regional stress field and the interaction of rising magma with pre-existing faults. The youngest eruptions in both volcanoes were complex, with shifts in the eruptive style from violent strombolian to hawaiian/strombolian phases, and probably lasted for a few years. The explosive activity was accompanied by the emission of lava flows from lateral vents. Phreatomagmatic activity was triggered during the waning stages of the eruptions. The occurrence of more than one eruption in a single scoria cone and the changes in the eruptive style during longlasting eruptions are important topics for volcanic hazard assessment in the Southern Puna.

The Cerro Blanco Caldera (CBC) is the youngest collapse caldera system in the Southern Central Andes (Southern Puna, Argentina). The CBC is subsiding with at an average velocity of 0.87 cm/year and hosts an active geothermal system. A geochemical characterization of emitted fluids was carried out based on the chemical and isotopic compositions of fumaroles, and thermal and cold springs discharged in this volcanic area with the aim of constructing the first hydrogeochemical conceptual model and preliminary estimate the geothermal potential. The main hydrothermal reservoir, likely hosted within the pre-caldera basement rocks, has a Na +-Clˉ(HCO 3)c omposition with estimated temperatures ≥135°C. The unconsolidated, fine-grained Cerro Blanco ignimbrite likely acts as the cap-rock of the hydrothermal system. The presence of phreatic eruption breccias in the surrounding area of the geothermal fumaroles supports the effectiveness of the pyroclastic deposit as sealing rocks. The isotopic data of water (δ 18 O and δD) indicate a meteoric recharge of the hydrothermal reservoir, suggesting as recharge areas the sectors surrounding the CBC, mainly towards the W and NW where large outcrops of the pre-caldera basement exist. A fault-controlled hydraulic connection between the hot springs and the hydrothermal reservoir is proposed for the Los Hornitos area. The fumaroles show the typical compositional features of hydrothermal fluids, being dominated by water vapor with significant concentrations of H 2 S, CH 4 and H 2. Considering the high geothermal gradient of this area (∼104°C/km) and the relatively high fraction of mantle He (∼39%) calculated on the basis of the measured R/Ra values, the hydrothermal aquifer likely receives inputs of magmatic fluids from the degassing magma chamber. The preliminary geothermal potential at CBC was evaluated with the Volume Method, calculating up to E = 11.4*10 18 J. Both the scarce presence of superficial thermal manifestations and the occurrence of an efficient cap-rock likely contribute to minimize the loss of thermal energy from the reservoir. The results here presented constitute the necessary base of knowledge for further accurate assessment of the geothermal potential and ultimately the implementation of the geothermal resource as a viable energy alternative for small localities or mining facilities isolated from the National Interconnected System due to their remote localization.

We report the results of a systematic study carried out on the fracture systems exposed in the Sierra de La Candelaria anticline, in the central Andean retrowedge of northwestern Argentina. The aim was to elaborate a kinematic model of the anticline and to assess the dimensional and spatial properties of the fracture network characterizing the Cretaceous sandstone reservoir of the geothermal system of Rosario de La Frontera. Special regard was devoted to explore how tectonics may affect fluid circulation at depth and control fluids' natural upwelling at surface. With this aim we performed a Discrete Fracture Network model in order to evaluate the potential of the reservoir of the studied geothermal system. The results show that the Sierra de La Candelaria regional anticline developed according to a kinematic model of transpressional inversion compatible with the latest Andean regional WNW–ESE shortening, acting on a pre-orogenic N–S normal fault. A push-up geometry developed during positive inversion controlling the development of two minor anticlines: Termas and Balboa, separated by further NNW–SSE oblique-slip fault in the northern sector of the regional anticline. Brittle deformation recorded at the outcrop scale is robustly consistent with the extensional and transpressional events recognized at regional scale. In terms of fluid circulation, the NNW–SSE and NE–SW fault planes, associated to the late stage of the positive inversion, are considered the main structures controlling the migration paths of hot fluids from the reservoir to the surface. The results of the fracture modeling performed show that fractures related to the same deformation stage, are characterized by the highest values of secondary permeability. Moreover, the DFN models performed in the reservoir volume indicates that fracture network enhances its permeability: its secondary permeability is of about 49 mD and its fractured portion represents the 0.03% of the total volume

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