Evaluating suitability of energy efficient and anti-stripping additives for polymer and Polyphosphoric acid modified asphalt binder using surface free energy approach

Singh, Dharamveer; Habal, Ayyanna; Ashish, Prabin Kumar; Kataware, Aniket V.

doi:10.1016/j.conbuildmat.2017.10.079

Cited by 28 publications

(10 citation statements)

References 28 publications

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“…It has also been reported in the studies that the use of terpolymers alone as a modifier is not ideal, because it may have a negative impact on the performance properties of binder due to the gelation [18,19,20,22]. When reactive terpolymers are used in bitumen modification, a certain amount of Polyphosphoric Acid (PPA) is usually added as a catalyst to accelerate the chemical reaction between bitumen and polymer in the mixture [17,18,20,23,24]. When PPA is used in the bitumen–polymer mixture, the amount of polymer needed for the modification is reduced and the performance characteristics of the modified bitumen, such as permanent deformation, aging and fatigue resistance, increase positively [17,18,19,20,21,24].…”

Section: Introductionmentioning

confidence: 99%

“…It was also seen that the additive percentages of terpolymer were higher (1–6%) when it was used alone [26,27,28,29,31,32,34], but were lower (0.4–1.6%) when it was used with PPA [14,17,18,20,24,25,28,30,38]. Moreover, the terpolymers were generally used in a single percentage and in combination with another polymer [17,18,20,24,28,30,31,34]. Although there have been studies using different percentages of terpolymer in the modification, PPA has been used in only two of them [25,38].…”

Section: Introductionmentioning

confidence: 99%

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Physical, Chemical, Microstructural and Rheological Properties of Reactive Terpolymer-Modified Bitumen

Geçkil

2019

Materials

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In this study, the change in the physical, chemical, microstructural, and rheological properties of a road bitumen modified with reactive terpolymer (Elvaloy®RET) was investigated. For this purpose, four different Elvaloy®RET percentages (0%, 0.4%, 0.8%, and 1.2% by wt.) were mixed with B 160/220 bitumen. Firstly, the obtained samples were subjected to a short and long-term aging process using a rotating thin-film oven test and pressurized aging vessel, respectively. Then, the engineering characteristics of the samples were investigated using X-ray diffraction, scanning electron microscopy, and conventional and Superpave bitumen tests. The results showed that Elvaloy®RET reacted with the main macromolecular groups in the bitumen, and that the modified bitumens behaved as a homogenous single phase structure as a result of this reaction. Conventional tests showed that Elvaloy®RET-modified bitumens were much harder than pure bitumen and had better aging resistance. Furthermore, the penetration classes of these bitumens changed and their temperature sensitivities decreased significantly. Rheological tests showed that the Elvaloy®RET additive increased the resistance of the bitumen against fatigue cracking and particularly permanent deformation. Moreover, the high temperature performance class of the bitumen also increased. However, parallel to the hardening of the bitumen, a reduction in its resistance to cracking at low temperature was observed.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Physical, Chemical, Microstructural and Rheological Properties of Reactive Terpolymer-Modified Bitumen

Geçkil

2019

Materials

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“…Among them, polyphosphoric acid (PPA) has gradually attracted researchers' attention. As a mixture of triphosphate pyrophosphate, PPA, and other advanced acids as well as inorganic compounds with high solubility [5], PPA has advantages such as low cost and simple processing technology, and it exhibits a good modification effect on asphalt [6], involving the improvement of the temperature sensitivity, high-temperature stability, and antiaging performance of matrix asphalt. Due to the above advantages of PPA, many scholars have studied it in recent decades.…”

Section: Introductionmentioning

confidence: 99%

Influence of PPA on the Short‐Term Antiaging Performance of Asphalt

Gao

Cai

et al. 2021

Advances in Civil Engineering

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It has been confirmed that polyphosphoric acid (PPA) can significantly improve the high-temperature resistance, storage stability, and aging resistance of asphalt. The low price of PPA is conducive to the development of modified asphalt with high performance and excellent economy, suggesting its great application prospects. At present, there is little research on the role of PPA in delaying the aging process of PPA-modified asphalt, and a consensus has not yet been reached. Therefore, PPA-modified asphalt with different blending amounts (0 wt%, 0.4 wt%, 0.8 wt%, and 1.2 wt%) was prepared in this study. On the basis of variable performance, the role of PPA in the short-term antiaging process of asphalt is analyzed through Fourier transform infrared spectroscopy (FTIR) analysis of PPA-modified asphalt before and after aging, combined with the analysis of the change in components. The results showed that after PPA addition, the high-temperature resistance and the thermal stability of asphalt were improved and the temperature sensitivity was weakened. Both curves of ductility and G ∗ indicate the potential saturation effect of PPA addition; together with infrared spectroscopy, we proved that there are both chemical reactions and physical mixing in the PPA-modified asphalt. The component fractions show that PPA will cause the asphalt to transform from sol to gel and the main function of PPA in retarding asphalt aging is the dispersion of the agglomerates of asphaltene micelles by PPA.

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“…Modifikasyonda RET ile asfalt bağlayıcı arasındaki kimyasal reaksiyonun hızlandırmak amacıyla çoğunlukla karışıma katalizör olarak fosforik asit ilave edilmektedir. Fosforik asit kullanımı ile karışımda kullanılabilen RET miktarı azalmakta ve karışımın tekerlek izi, yaşlanma ve yorulma direnci ayrıca artış göstermektedir [20][21][22]. RET kullanılarak yapılan çalışmalarda modifiye asfaltların kıvamlarında sertleşme meydana geldiği, sıcaklık hassasiyetlerinin azaldığı, kalıcı deformasyon ve yorulma dirençlerinin arttığı görülmüştür.…”

Section: Introductionunclassified

Sıcak Karışım Asfalt Kaplamanın Su Hasarı Direnci Üzerinde RET Katkısının Etkisi

Geçkil

2021

Fırat Üniversitesi Mühendislik Bilimleri Dergisi

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Öz: Bu çalışmada, reaktif terpolimer (RET) katkılı sıcak karışım asfalt kaplamaların su etkilerine karşı direnci üzerinde reaktif terpolimer (RET) katkısının etkileri araştırılmıştır. Bu amaçla, penetrasyon sınıfı B 100/150 olan saf asfalta ağırlıkça %0,5; %0,75 ve %1 oranlarında RET (Elvaloy 4170) eklenerek modifiye asfaltlar hazırlanmıştır. Modifiye asfaltların fiziksel özellikleri penetrasyon, yumuşama noktası ve düktilite deneyleri ile, işlenebilirlik özellikleri ise dönel viskozimetre (RV) deneyi ile belirlenmiştir. Daha sonra, karışım tasarımı için agrega ve saf asfalt kullanılarak Marshall yöntemine göre karışımın optimum asfalt içeriği belirlenmiştir. Belirlenen bu oran sabit tutularak saf ve modifiye asfaltlar ile sıcak karışım numuneleri hazırlanmıştır. Hazırlanmış olan saf ve RET katkılı modifiye karışım numuneleri Marshall stabilitesi, kalıcı Marshall stabilitesi (RMS) ve dolaylı çekme mukavemeti (ITS) deneylerine maruz bırakılmıştır. Asfalt test sonuçlarına göre, RET katkısı ile modifiye bağlayıcıların sertliğinin ve karıştırma-sıkıştırma sıcaklıklarının arttığı görülmüştür. Karışım sonuçlarına göre, özellikle %0,75 katkılı karışımların Marshall stabilitesi, RMS ve dolaylı çekme mukavemeti oranı (ITSR) değerlerinin önemli artışlar göstermesi sebebiyle yol kaplamalarının suya karşı hassasiyeti üzerinde RET katkısının iyileştirici bir etki gösterdiği görülmüştür.

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Evaluating suitability of energy efficient and anti-stripping additives for polymer and Polyphosphoric acid modified asphalt binder using surface free energy approach

Cited by 28 publications

References 28 publications

Physical, Chemical, Microstructural and Rheological Properties of Reactive Terpolymer-Modified Bitumen

Physical, Chemical, Microstructural and Rheological Properties of Reactive Terpolymer-Modified Bitumen

Influence of PPA on the Short‐Term Antiaging Performance of Asphalt

Sıcak Karışım Asfalt Kaplamanın Su Hasarı Direnci Üzerinde RET Katkısının Etkisi

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