Padé approximation is the rational generalization of Hermite interpolating polynomial. On its own merits, it has earned a relevant place in the theory of constructive approximation. In this article we will develop an exhaustive analysis of two-point Padé approximations to Herglotz-Riesz transforms. We study the convergence problem when the poles are partially preassigned. In this analysis the Stieltjes polynomials on the unit circle naturally arise. Finally, some illustrative numerical examples are discussed.