2007
DOI: 10.1002/chin.200740085
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Norma A. Cortez,
Gerardo Aguirre,
Miguel Parra-Hake
et al.

Abstract: Alcohols Q 0230Water-Soluble Chiral Monosulfonamide-cyclohexane-1,2-diamine-RhCp* Complex and Its Application in the Asymmetric Transfer Hydrogenation (ATH) of Ketones. -Ligands (I) are synthesized and tested in the title reaction of acetophenone (II). With exception of (If) (12% e.e.), nearly identical results (89-94%% e.e.) are obtained. The derivative (Ia) is applied in the transformation of various ketones. Remarkable improvement in enantioselectivity and yield on addition of surfactants is observed in so…

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