“…[1] Polycarboxylic acid inhibitor, such as maleic acid and acrylic acid homo-and co-polymers, is well known in the industry as one type of efficient and threshold carbonate scale inhibitors which are becoming increasingly important due to phosphorus-free and less toxic to environment. [2,3] However, owing to the weak acidity of the carboxylic acid that is relatively difficult to form negative ion in water, polycarboxylic acid inhibitor have low calcium tolerance and readily react with calcium ions to form insoluble calcium polymer salts. [4] Introduction of hydrophilic group (such as sulfonic acid group, [5] ethylene oxide group, [6] or like) into polycarboxylic acid molecule might improve its water solubility, enhance calcium tolerance and prevent formation of insoluble calcium polymer salts.…”