“…Such hierarchically porous wood structure provides an excellent platform for investigating multiscale ion transport and regulation through suitable physical and/or chemical modification, enabling its applications in various types of devices. Recently, multiscale‐engineered wood‐based structures for various ion‐based applications have been demonstrated, including ion‐intercalated cellulosic membrane with unconventional super high ion conductivity and charge selectivity by opening up sub‐nanometer molecular channels, [ 77 ] surface carbonized bilayer wood block for high efficiency continuous solar desalination, [ 153–155 ] metallic nanoparticle decorated wood membrane for high flux water treatment, [ 72,156–158 ] and electrode material hybridized wood for cost‐effective energy storage. [ 104,114,159–161 ] The benefits provided by the multiscale‐engineered wood‐based structures can be utilized toward developing ion‐water‐based emerging technologies ( Figure ), such as: 1) mechanically robust ion selective/regulation membranes for a range of energy applications (e.g., batteries, supercapacitors, salinity gradient power generation and thermal energy harvesting); ) wood‐based 2D and 3D devices that simultaneously ensure high flux and high ion‐removal efficiency for water filtration (with a particular focus on the removal of heavy metal ions) and water desalination (with a particular focus on salt‐rejection solar desalination devices); and ) functional wood‐based devices with targeted signaling and sensing functions (e.g., strain and humidity sensors, transistors, and biological systems).…”