“…44 Briefly, the Fe n BO 2 − ͑n=1-10͒ cluster anions were produced in a laser vaporization source by ablating a rotating, translating B/Fe alloy target ͑13 mm diameter, Fe/B mole ratio of 50:1͒ with the second harmonic ͑532 nm͒ light pulses of a Nd:YAG ͑yttrium aluminum garnet͒ laser, while helium gas with 4 atm was allowed to expand through a pulsed valve over the alloy target. The residual oxygen on the target surface was sufficient to produce abundant Fe n BO 2 − clusters, so no additional oxygen was introduced into the source.…”