1970
DOI: 10.1016/s0008-6215(00)80833-2
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Unsaturated carbohydrates

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1971
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Cited by 32 publications
(2 citation statements)
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“…The extrusion of glycolic aldehyde from the 228 ion is consistent with the results of Ferrier and co-workers. 21 An additional mode of fragmentation of 7a begins with the familiar22 loss of the aglycon to give a m/e 295 ion. The subsequent decomposition of this ion is detailed in Scheme II.…”
Section: Resultsmentioning
confidence: 99%
“…The extrusion of glycolic aldehyde from the 228 ion is consistent with the results of Ferrier and co-workers. 21 An additional mode of fragmentation of 7a begins with the familiar22 loss of the aglycon to give a m/e 295 ion. The subsequent decomposition of this ion is detailed in Scheme II.…”
Section: Resultsmentioning
confidence: 99%
“…obtained the same ion 270 at m/e 98 regardless of C-5 and C-6 deuterium label. Other structurally related compounds for which the retrodiene breakdown under electron impact has been proposed are cyclohexenones,260,2615,6-dihydropyrans,262 and 2,3-unsaturated monosaccharides 257. …”
mentioning
confidence: 99%