2015
DOI: 10.1021/jacs.5b02480
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Abstract: Searching for new chemically durable and radiation-resistant absorbent materials for actinides and their fission products generated in the nuclear fuel cycle remain highly desirable, for both waste management and contamination remediation. Here we present a rare case of 3D uranyl organic framework material built through polycatenating of three sets of graphene-like layers, which exhibits significant umbellate distortions in the uranyl equatorial planes studied thoroughly by linear transit calculations. This un… Show more

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Cited by 390 publications
(335 citation statements)
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“…During the past decade, significant amounts of works have been devoted to designing and synthesizing MOFs that are resistant to structural degradation induced by moisture, acids/bases, oxidants/reductants and radiation, critical features for many practical applications12345. To achieve these goals, Pearson hard and soft acid and base theory was followed67.…”
mentioning
confidence: 99%
“…During the past decade, significant amounts of works have been devoted to designing and synthesizing MOFs that are resistant to structural degradation induced by moisture, acids/bases, oxidants/reductants and radiation, critical features for many practical applications12345. To achieve these goals, Pearson hard and soft acid and base theory was followed67.…”
mentioning
confidence: 99%
“…ap olycatenated uranyl MOF compound, [18] and provides an essential prerequisite for potential applications as aradiation dosimeter.I na ddition, complete recovery of quenched photoluminescence can be achieved by heating the irradiated sample of 1 at 200 8 8Cf or 12 h ( Figures 2d and S11).…”
mentioning
confidence: 99%
“…Supercritical CO 2 drying [2,4,24] was employed to evacuate the NU-1300 structure.See Supporting Information for details.N itrogen adsorption experiments,p erformed on an optimally activated sample of NU-1300, exhibits atype IV isotherm consistent with mesoporosity ( Figure 2). [19,26] To probe the charge of the pore surface within NU-1300, three cationic organic dyes,m ethylene blue (MEB), Janus Green B(JB), ethyl violet (EV), and an anionic organic dye, resorufin sodium salt (RS), were chosen as diagnostic agents. 800 cm 3 g À1 )a nd following the consistency criteria, [25] we calculated aB runauer-Emmett-Teller (BET) surface area of 2100 m 2 g À1 ( Figure S2 and Table S3).…”
mentioning
confidence: 99%