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2009
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Cited by 31 publications
(9 citation statements)
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“…Applications of Ozone in Organic Synthesis. ± Harries exploited the ozonolysis reaction for the synthesis of a variety of difficultly obtainable substances including levulinaldehyde [13], glyoxal and its monoacetal [27], methylgyloxal [28], mesoxaldehyde [27], biacetyl carboxylic acid [29], and succinic acid semi-aldehyde [30], among others. While these were significant achievements, the work was severely hampered by the finding that the usual procedure for decomposition of ozonides, heating with H 2 O, afforded H 2 O 2 as well as ketones, and both aldehydes and acids in compounds having a H-atom at either terminus of the double bond.…”
Section: Reaction Of O 3 With Organicmentioning
confidence: 99%
“…Applications of Ozone in Organic Synthesis. ± Harries exploited the ozonolysis reaction for the synthesis of a variety of difficultly obtainable substances including levulinaldehyde [13], glyoxal and its monoacetal [27], methylgyloxal [28], mesoxaldehyde [27], biacetyl carboxylic acid [29], and succinic acid semi-aldehyde [30], among others. While these were significant achievements, the work was severely hampered by the finding that the usual procedure for decomposition of ozonides, heating with H 2 O, afforded H 2 O 2 as well as ketones, and both aldehydes and acids in compounds having a H-atom at either terminus of the double bond.…”
Section: Reaction Of O 3 With Organicmentioning
confidence: 99%
“…In 1905, Harries et al reported [11] the preparation of mesoxaldehyde (or 2-oxo-1,3-propanedial) as a polymer from phorone or dibenzalacetone [12] and studied it in the gas phase, but found that it quickly polymerized. For this reason, the development of 2-oxo-1,3-propanedial derivatives is a continuous challenge to many chemists.…”
Section: Introductionmentioning
confidence: 98%
“…Compare Abstr., 1903, i, 799 ;1904, i, Nitriles of Hydroxy-and Amino-carboxylic Acids. EMIL KNOEVENAGEL (Ber., 1905, 38, 213-217. Compare Trans., 1904, i, 981, 989, 994, 1024, 1027, 1028.-Polemical.…”
Section: Imino-cc-dialkylbarbituricmentioning
confidence: 99%
“…9 : 10-Diphenylphenanthrene. HEINRICH BILTZ (Ber., 1905, 38, 203-206. Compare Abstr., 18931897, i, 533).-The compound melting a t 235' (corr.)…”
Section: J J Smentioning
confidence: 99%
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