A γ-ray spectroscopy study of excited states in 26 Si has been performed using the 24 Mg( 3 He,n) reaction at a beam energy of 10 MeV. In particular, states have been studied above the proton threshold relevant for burning in the 25 Al(p,γ) 26 Si reaction in novae. This reaction influences the amount of 26 Al injected into the interstellar medium by novae, which contributes to the overall flux of cosmic gamma-ray emission from 26 Al observed in satellite missions. The present results point strongly to the existence of a 0 + state at an excitation energy of 5890 keV lying within the Gamow burning window, which raises questions about the existence and properties of another, higher-lying state/resonance reported in previous experimental work. The existence of two such states within this excitation energy region cannot be understood in the framework of sd shell-model calculations.