Two-Dimensional NMR of Molecules Oriented in Liquid Crystals-Recent Developments

S-Mg2(dobpdc): a metal–organic framework for determining chirality in amino acids

“…The use of solid-state NMR for the quantification of chirality is underdeveloped, with the main focus in this area concerning the use of liquid crystals as a chiral matrix. 8,9 Coordination Polymers (CPs) and Metal Organic Frameworks (MOFs) are crystalline solid materials comprising of metal ions bridged by organic ligands in 1D, 2D or 3D to create a scaffold containing pores. 4 Chiral MOFs and CPs are typically used as stationary chiral phases for HPLC 5 or as heterogenous asymmetric catalysts.…”