Three d10 metal coordination compounds based on pyrazole-3-carboxylic acid showing mixed-ligand characteristic: Syntheses, crystal structures, and photoluminescent properties

Synthesis, structure and characterization of a layered coordination polymer based on Zn(ii) and 6-(methylmercapto)purine

“…As nucleobases contain multiple donor sites, they can act as ligands in coordination networks useful in medicine, industry, agriculture and coordination chemistry. 26 There are several examples of LCPs based on Zn [27][28][29][30][31][32][33][34][35][36][37] or nucleobases, [38][39][40][41][42][43][44] but just a few based on the Zn and nucleobase combination. 45,46 Here, we report the synthesis and characterization of a new LCP named UZAR-S12 (henceforth referred to as 1).…”

Investigation of the crystal structure and electrochemical properties of catena-poly[[chlorido(piperazin-1-ium–κN))cadmium(II)]-di-μ-chlorido]monohydrate

“…The luminescence properties of complexes with d 10 metal centers are of much interest because of their potential applications in photochemistry, as chemical sensors, and in electroluminescent displays [30,31]. Therefore, the luminescence of the complex was investigated in the solid state at room temperature.…”

High Efficiency Electrochemiluminescence for Copper(II) and Cadmium(II) Pyrazolate Polymers

“…However, it is a great challenge to control the structures and construct the target molecules with desired properties [14], owing to temperature, pH value and solvent will also affect the structure of resulting crystals [15,16]. Among the numerous organic ligands, pyrazole carboxylate ligands obtained widely concern due to possessing N-donors in pyrazole ring and O atoms on the carboxylate which can provide potential coordination nodes and can exhibit flexible chelating and bridging coordination modes [17,18]. What's more, act as multiple proton donors, deprotonated ligands can increase the coordination site which can help to fabricate high-dimensional coordination polymers.…”