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The arrangement of this Chapter is broadly similar to that used in previous years so that, following this introduction, there are three main sections. The first of these is concerned with scandium and the second with yttrium and the lanthanides. This latter section is subdivided under the topic headings 'Oxides and Solid State Studies', 'Catalysts and Reagents*, 'Solution Studies*, 'Luminescence Studies', 'Coordination Compounds*, and 'Organolanthanide Compounds*. The third and final section on the actinide elements is subdivided under the headings 'General and Coordination Chemistry' and 'Organoactinide Chemistry'. The emphasis in this report has been placed primarily on molecular species and, following the precedent of previous years, papers relating solely to stability constant measurements and studies of binary or ternary compounds have, in the main, not been included.During the year there have been two additions to Gmelin's Handbook of Inorganic Chemistry which relate to f-block elements. The first of these is entitled 'Alloys of Uranium with Alkali Metals, Alkaline Earths, and Elements of Main Groups I11 and IV' and describes alloys and intermetallic compounds of uranium formed with some main group elements.' Binary, and some ternary, systems are covered and there is a chapter on UBeI3. Cermets and alloys of the U-Al system, important in high neutron flux research reactors, are also included. The second volume is entitled 'General Properties, Spectra, and Recoil Reactions' and brings together the properties of thorium, including electronic structure, ionic radii, and ionization potentiak2 Thermodynamic properties, recoil reactions, and the effects of ionizing radiation on thorium alloys are also covered. Although not strictly associated with the f-block elements, a book has appeared which considers the theoretical bases for predicting the stabilities of superheavy elements and the approaches used for their p r e p a r a t i ~n . ~The design and synthesis of lanthanide(II1) complexes with 18-membered ring N,-macrocycles has been r e ~i e w e d . ~Reviews have also appeared on the preparation, structures, and properties of the actinide^,^ on the coordination compounds of Np
The arrangement of this Chapter is broadly similar to that used in previous years so that, following this introduction, there are three main sections. The first of these is concerned with scandium and the second with yttrium and the lanthanides. This latter section is subdivided under the topic headings 'Oxides and Solid State Studies', 'Catalysts and Reagents*, 'Solution Studies*, 'Luminescence Studies', 'Coordination Compounds*, and 'Organolanthanide Compounds*. The third and final section on the actinide elements is subdivided under the headings 'General and Coordination Chemistry' and 'Organoactinide Chemistry'. The emphasis in this report has been placed primarily on molecular species and, following the precedent of previous years, papers relating solely to stability constant measurements and studies of binary or ternary compounds have, in the main, not been included.During the year there have been two additions to Gmelin's Handbook of Inorganic Chemistry which relate to f-block elements. The first of these is entitled 'Alloys of Uranium with Alkali Metals, Alkaline Earths, and Elements of Main Groups I11 and IV' and describes alloys and intermetallic compounds of uranium formed with some main group elements.' Binary, and some ternary, systems are covered and there is a chapter on UBeI3. Cermets and alloys of the U-Al system, important in high neutron flux research reactors, are also included. The second volume is entitled 'General Properties, Spectra, and Recoil Reactions' and brings together the properties of thorium, including electronic structure, ionic radii, and ionization potentiak2 Thermodynamic properties, recoil reactions, and the effects of ionizing radiation on thorium alloys are also covered. Although not strictly associated with the f-block elements, a book has appeared which considers the theoretical bases for predicting the stabilities of superheavy elements and the approaches used for their p r e p a r a t i ~n . ~The design and synthesis of lanthanide(II1) complexes with 18-membered ring N,-macrocycles has been r e ~i e w e d . ~Reviews have also appeared on the preparation, structures, and properties of the actinide^,^ on the coordination compounds of Np
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