Vladimir L. Kuznetsov, Anna N. Usoltseva, Andrew L. Chuvilin, Elena D. Obraztsova, Jean-Marc Bonard
Abstract:AbstractA thermodynamic analysis of the carbon nucleation on the metal surface was performed. From the consideration of the catalytic mechanisms of carbon deposit formation on the metal surface we concluded that majority of these mechanisms include some common steps. The most important of them is the step of nucleation of carbon deposit on the metal surface. The master equation for the dependence of critical radius of the nucleus on reaction parameters was obtained. This equation demonstrates that a variation …
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