Thermally Conductive and Shape‐Stabilized Polyethylene Glycol/Carbon Foam Phase‐Change Composites for Thermal Energy Storage

Abstract

Phase‐change materials (PCMs) have been widely investigated as candidates for thermal energy storage and solar thermal energy conversion. However, low thermal conductivity and poor shape stability during phase transition processes are detrimental to their practical applications. In this study, we designed composite PCMs based on carbon foam (CF) via the vacuum impregnation method to overcome these problems. CF with 3D interconnected microporous structures and good compressive strength was fabricated from phenolic resin (PF) using a combined process of carbonization and sacrificial template techniques. The developer material is considered a promising support material for PCMs. The as‐prepared polyethylene glycol/CF composite (PCC) exhibited a high energy‐storage density with a melting enthalpy of 135.7 J/g, and the thermal conductivity was enhanced by 109.8% compared to that of pure polyethylene glycol. In addition, the PCC showed excellent thermal stability and leakage‐proof performance after 100 heating/cooling cycles and good compressive strength. Because of the simple preparation process and low cost, PCC is a promising material for various thermal energy storage applications, especially in building energy storage systems.

Design and Construction of Photochromic and Antileakage Reinforced Wood-Based Cellulose Microframework/Hexadecanol-Coconut Oil Composite Phase Change Material

“…11 To obtain SPCMs, in addition to the microcapsule method, it is also an effective way to use the microscopic pore structure of the framework support material to realize the encapsulation of phase change materials. 12 Current research in this field mainly focuses on the use of biomass carbon materials, 13 inorganic nonmetals, 14 montmorillonite, 15 delignified wood, 12 diatomaceous earth, 16 carbon foam, 17 radial mesoporous silica sphere, 18 etc. as framework support materials.…”

Introduction of Phase Change Material into Sustainable Carbon Materials for Enhanced Shape Stability and Thermal Conductivity

“…However, the thermal conductivity of the composites was not reported . In the past few years, porous carbon materials, including carbon nanotubes aerogel, graphene aerogel, carbon foam, and biomass‐derived porous carbon materials, were applied to comprehensively modifying the thermal conductivity together with preventing the leakage. Such porous carbon materials play pivotal roles in various fields due to their three‐dimensional structures with distinguished properties, such as high porosity, low density, and high thermal conductivity, etc .…”