Thermal stabilities of di-alkylimidazolium chloride ionic liquids

Kamavaram, Venkat; Reddy, Ramana G.

doi:10.1016/j.ijthermalsci.2007.06.012

Cited by 93 publications

(57 citation statements)

References 23 publications

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“…It has been further demonstrated that ILs show lower thermal stability when heated isothermally for a long time. Thus, the decomposition of alkyl-substituted imidazolium ILs with the chloride anion is observed at much lower temperatures (200°C) than those specified in the literature (T onset = 350°C) [24,25].…”

Section: Vapor Pressure and Thermal Stability Of Ilsmentioning

confidence: 72%

Opportunities and shortcomings of ionic liquids in single-drop microextraction

Marcinkowski

Pena‐Pereira

Kloskowski

et al. 2015

TrAC Trends in Analytical Chemistry

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Section: Vapor Pressure and Thermal Stability Of Ilsmentioning

confidence: 72%

Opportunities and shortcomings of ionic liquids in single-drop microextraction

Marcinkowski

Pena‐Pereira

Kloskowski

et al. 2015

TrAC Trends in Analytical Chemistry

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“…The thermal stability of IL electrolytes determines the usable temperature range of IL-based supercapacitors. Because of the non-boiling characteristics, the upper temperature limit to which that ILs can be safely used depends on the thermal degradation temperature point, which can be measured by thermogravimetric analysis [62] and isothermal gravimetrical analyses [63]. Various factors such as salt structures, environment, and even electrodes materials can influence the thermal stability of ILs [57].…”

Section: Thermal Stability Of Il Electrolytesmentioning

confidence: 99%

Influence of Temperature on Supercapacitor Components

Xiong

Kundu

Fisher

2015

Thermal Effects in Supercapacitors

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Among the major thermophysical properties of electrolytes, thermal stability and ionic conductivity are the most two crucial properties in determining the thermal performance of supercapacitors. The former determines the usable temperature range of supercapacitor devices, and the latter dictates the electrochemical performance at different temperatures. This section generally introduces the relationships among the critical thermophysical properties of electrolytes, followed by a discussion of the thermal stability and ionic conductivity of different common electrolytes.

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“…They suggested that the promoted yield of HMF would be due to the rapid conversion rates of sugar to HMF facilitated probably by sugar-metal coordination in ionic liquids. Because ionic liquids have some such properties favorable to chemical reactions as high thermal stability, low vapor pressure, a wide solvating property in the aqueous phase, and low melting points, they are currently used as both solvent and catalyst [12,13]. An ionic liquid, 1-octyl-3-methylimidazolium chloride ([OMIM]Cl), a derivative of disubstituted imidazolium chloride ionic liquids, positively affected the synthesis of HMF from starch.…”

Section: Introductionmentioning

confidence: 99%