2000
DOI: 10.1002/1099-0488(20000701)38:13<1699::aid-polb30>3.3.co;2-c
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Thermal, mechanical, and morphological properties of phenolic resin/silica hybrid ceramers
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Abstract
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“…13,20 The numerous mechanistic parallels between alkoxysilane hydrolysis-condensation reactions and resorcinol-formaldehyde (RF) base-catalyzed polymerization led many researchers to the development of synthetic procedures to concurrently polymerize silica precursors and RF resins. Following this strategy, bulk polymer/silica hybrid ceramics, 21,22 nanocomposites 23,24 and aerogels 25 were synthesized. In a similar fashion, the Zhao group has introduced a family of 2D 6 and 3D 26 ordered mesoporous polymer/silica and carbon/silica nanostructures and films 27 via the surfactant-assisted simultaneous polycondensation of low molecular weight phenolic resins (resols) and tetraethylorthosilicate (TEOS).…”
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confidence: 84%