“…Etna characterized by uniform phase assemblages (olivine + clinopyroxene + plagioclase + titanomagnetite) and bulk rocks permanently buffered to the compositions of trachybasalts and basaltic trachyandesites (Armienti et al, 2007;Corsaro et al, 2009). To provide magmatic constraints on the early-stage of crystallization, the compositions of phenocryst cores and bulk rocks are frequently used as input data for barometers, thermometers, hygrometers and oxygen barometers (Armienti et al, 2007(Armienti et al, , 2013Lanzafame et al, 2013;Ferlito et al, 2014;Giacomoni et al, 2014;Mollo et al, 2015). However, these estimates reflect the conditions at which minerals saturate the melt at low degrees of crystallization (Putirka et al, 2003), and when the erupted products represent near-liquidus compositions (Frey and Lange, 2011).…”