The thermal decomposition reactions of [Co(en)n(phen)m]Cl3 complexes

Thermal decomposition of [Co(NH3)6]Cl3

“…These data are generally consistent with those published earlier [2,4,5,[15][16][17]. The temperatures of the DTA peaks (stages I and II) are close to those reported by Wendlandt (553:648 K--He atm 0 and Watt (567: 614--N 2 atm.)…”

“…In the fourth stage, Co304 is transformed to CoO, which is in agreement with the literature data [16,21]. In the fourth stage, Co304 is transformed to CoO, which is in agreement with the literature data [16,21].…”

“…The thermogravimetric results obtained for [Co(NH3)6]CI 3 decomposition under quasi-isothermal conditions ( Table 2) in air and nitrogen atmospheres confirm the non-isothermal experimental data. It is commonly known and has been confirmed that all reactions of thermal decomposition of ammine-and aminecobalt(III) complexes involve the reduction of Co(III) to Co(II) [2,4,12,[15][16][17][18]. It is commonly known and has been confirmed that all reactions of thermal decomposition of ammine-and aminecobalt(III) complexes involve the reduction of Co(III) to Co(II) [2,4,12,[15][16][17][18].…”

The thermal decomposition reactions of bis-(pyridine-2-aldoxime)-copper(II) complexes

“…Following thermoanalytical studies of the complexes of 3 d metal ions with organic ligands [8][9][10][11], in this paper we report results on the thermal behaviour of the complexes [Cu(C6H5N20)2Hn]CI n (where n = 0, 1 or 2). The study has been carried out by thermogravimetry, differential thermal analysis and mass spectrometry; the proposed decomposition mechanisms are supported by analysis of the stable intermediates obtained by interruption of the heating of the samples at the appropriate temperatures.…”

Thermoanalytical behaviour of some dicarboxylato-α-diiminecobalt(III) complexes

“…It is to be noted that this work follows thermoanalytical studies in our laboratory on other cobalt(HI) complexes with nitrogen ligands [3][4][5].…”