The synthesis and characterization of novel tetraoxime and its mono- and polynuclear complexes containing 12-membered diaza-dithia macrocycles

Synthesis, characterization and liquid–liquid extraction properties of new methoxyaminobiphenylglyoxime derivatives and their complexes with some transition metals

“…Technetium(V)-and copper(II)-containing vic-dioximes currently are used as cerebral and myocardial perfusion imaging agents [6]. Oxime complexes of rare-earth elements, especially uranium and lutetium, are of particular interest for their optical, conductive, mesogene and redox properties [7][8][9][10][11][12]. The ability of oxime-containing ligands to stabilize particular metal ion redox states is vitally important in their role in bioinorganic systems.…”

Synthesis, characterization and liquid–liquid extraction properties of new methoxyaminobiphenylglyoxime derivatives and their complexes with some transition metals

“…Technetium(V)-and copper(II)-containing vic-dioximes currently are used as cerebral and myocardial perfusion imaging agents [6]. Oxime complexes of rare-earth elements, especially uranium and lutetium, are of particular interest for their optical, conductive, mesogene and redox properties [7][8][9][10][11][12]. The ability of oxime-containing ligands to stabilize particular metal ion redox states is vitally important in their role in bioinorganic systems.…”

Liquid‐Liquid Extraction of Transition Metal Cations by Glyoximes and Their Macrocyclic Glyoxime Ether Derivatives

“…The presence of both mildly acidic hydroxyl groups and slightly basic nitrogen atoms makes ( , )-dioximes amphoteric ligands which form corrin-type square planar, square pyramidal, and octahedral complexes with nickel(II), cobalt(II), copper(II), palladium(II), and cobalt(III) as central metal atoms [6][7][8][9][10][11][12][13][14][15][16][17].…”

A water-soluble multisite ionophore ligand bearing pyridine and aminothiophenol functionality. Synthesis, spectroscopy and electrochemistry of its complexes, and peripheral reactivity of the (E,E)M (M = Ni) complex with Pd2+ and Ag+

“…Although a large number of vic-dioxime complexes with structural types, such as MS 2 , MN 2 , MN 4 , MN 2 S 2 , MS 4 , MN 2 S 2 , MN 2 S 2 O 2 , MO 4 S 2 , etc have been synthesized and characterized previously [7,18,20,27,28], water soluble ones are rather scarce. The introduction of functional groups, such as pyridyl or quaternary ammonium on the periphery of the vic-dioxime makes the complexes soluble in water and gives rise to effective ionophore chelating capability with a variety of soft metal ions [29,30].…”

Synthesis, characterization and liquid–liquid extraction properties of new methoxyaminobiphenylglyoxime derivatives and their complexes with some transition metals

“…Technetium(V)-and copper(II)-containing vic-dioximes currently are used as cerebral and myocardial perfusion imaging agents [6]. Oxime complexes of rare-earth elements, especially uranium and lutetium, are of particular interest for their optical, conductive, mesogene and redox properties [7][8][9][10][11][12]. The ability of oxime-containing ligands to stabilize particular metal ion redox states is vitally important in their role in bioinorganic systems.…”

Liquid‐Liquid Extraction of Transition Metal Cations by Glyoximes and Their Macrocyclic Glyoxime Ether Derivatives

“…The presence of both mildly acidic hydroxyl groups and slightly basic nitrogen atoms makes ( , )-dioximes amphoteric ligands which form corrin-type square planar, square pyramidal, and octahedral complexes with nickel(II), cobalt(II), copper(II), palladium(II), and cobalt(III) as central metal atoms [6][7][8][9][10][11][12][13][14][15][16][17].…”

A water-soluble multisite ionophore ligand bearing pyridine and aminothiophenol functionality. Synthesis, spectroscopy and electrochemistry of its complexes, and peripheral reactivity of the (E,E)M (M = Ni) complex with Pd2+ and Ag+

“…Although a large number of vic-dioxime complexes with structural types, such as MS 2 , MN 2 , MN 4 , MN 2 S 2 , MS 4 , MN 2 S 2 , MN 2 S 2 O 2 , MO 4 S 2 , etc have been synthesized and characterized previously [7,18,20,27,28], water soluble ones are rather scarce. The introduction of functional groups, such as pyridyl or quaternary ammonium on the periphery of the vic-dioxime makes the complexes soluble in water and gives rise to effective ionophore chelating capability with a variety of soft metal ions [29,30].…”

Synthesis, characterization and liquid–liquid extraction properties of new methoxyaminobiphenylglyoxime derivatives and their complexes with some transition metals

“…Technetium(V)-and copper(II)-containing vic-dioximes currently are used as cerebral and myocardial perfusion imaging agents [6]. Oxime complexes of rare-earth elements, especially uranium and lutetium, are of particular interest for their optical, conductive, mesogene and redox properties [7][8][9][10][11][12]. The ability of oxime-containing ligands to stabilize particular metal ion redox states is vitally important in their role in bioinorganic systems.…”

Liquid‐Liquid Extraction of Transition Metal Cations by Glyoximes and Their Macrocyclic Glyoxime Ether Derivatives

“…The presence of both mildly acidic hydroxyl groups and slightly basic nitrogen atoms makes ( , )-dioximes amphoteric ligands which form corrin-type square planar, square pyramidal, and octahedral complexes with nickel(II), cobalt(II), copper(II), palladium(II), and cobalt(III) as central metal atoms [6][7][8][9][10][11][12][13][14][15][16][17].…”

A water-soluble multisite ionophore ligand bearing pyridine and aminothiophenol functionality. Synthesis, spectroscopy and electrochemistry of its complexes, and peripheral reactivity of the (E,E)M (M = Ni) complex with Pd2+ and Ag+

“…Although a large number of vic-dioxime complexes with structural types, such as MS 2 , MN 2 , MN 4 , MN 2 S 2 , MS 4 , MN 2 S 2 , MN 2 S 2 O 2 , MO 4 S 2 , etc have been synthesized and characterized previously [7,18,20,27,28], water soluble ones are rather scarce. The introduction of functional groups, such as pyridyl or quaternary ammonium on the periphery of the vic-dioxime makes the complexes soluble in water and gives rise to effective ionophore chelating capability with a variety of soft metal ions [29,30].…”